9-anthracenyl trifluoroacetate

Base Information

• Chemical Name: 9-anthracenyl trifluoroacetate
• CAS No.: 133512-49-9
• Molecular Formula: C₁₆H₉F₃O₂
• Molecular Weight: 290.241
• Mol file: 133512-49-9.mol

Synonyms:9-anthracenyl trifluoroacetate

Chemical Property of 9-anthracenyl trifluoroacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-anthracenyl trifluoroacetate

There total 3 articles about 9-anthracenyl trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

anthracene (120-12-7) + trifluoroacetic acid (76-05-1) → 9-nitroanthracene (602-60-8) + bianthronyl (434-84-4) + 9,10-phenanthrenequinone (84-65-1) + 9-anthracenyl trifluoroacetate (133512-49-9)

Guidance literature:

With methanol; oxygen; nitrosonium tetrafluoroborate; In dichloromethane; at 25 ℃; for 20h; Product distribution; Mechanism; various additives and concentrations of CF₃COOH, other reagents, other times;

Reference yield:

4a-acetyl-1,4,4a,9,9a,10-hexahydro-9,10-o-benzenoanthracene-1,4-dione (79755-94-5) → 9-anthrol (529-86-2) + anthracen-9(10H)-one (90-44-8) + 9-anthracenyl trifluoroacetate (133512-49-9) + 2-acetyl-5,6-dichlorohydroquinone (79755-97-8)

Guidance literature:

With trifluoroacetic acid; for 1h; Ambient temperature;

DOI:10.1039/P19810002670

Reference yield:

4a-acetyl-1,4,4a,9,9a,10-hexahydro-9,10-o-benzenoanthracene-1,4-dione (79755-94-5) + trifluoroacetic acid (76-05-1) → 9-anthrol (529-86-2) + anthracen-9(10H)-one (90-44-8) + 9-anthracenyl trifluoroacetate (133512-49-9) + 2-acetyl-5,6-dichlorohydroquinone (79755-97-8)

Guidance literature:

for 1h; Ambient temperature;

DOI:10.1039/P19810002670

upstream raw materials:

4a-acetyl-1,4,4a,9,9a,10-hexahydro-9,10-o-benzenoanthracene-1,4-dione

anthracene

trifluoroacetic acid

Refernces

• 1、 Beddoes, Roy L.,Bruce, J. Malcolm,Finch, Harry,Heelam, Leslie M. J.,Hunt, Ian D.,Mills, Owen S.. "Benzoquinones and Related Compounds. Part 4. Thermolysis of the Diels-Alder Adduct of 2-Acetyl-5,6-dichloro-1,4-benzoquinone and Cyclopentadiene: Evidence for a Partial Retro-diene Reaction". . p. 2670 - 2676. Retrieved 2007/10/02.