Triethylgermanium chloride

Base Information

• Chemical Name: Triethylgermanium chloride
• CAS No.: 994-28-5
• Molecular Formula: C6H15ClGe
• Molecular Weight: 195.228
• Hs Code.: 29319090
• European Community (EC) Number: 213-614-0
• NSC Number: 158926
• UNII: 3M5C1118J0
• DSSTox Substance ID: DTXSID3049382
• Nikkaji Number: J209.030I
• Wikidata: Q27257622
• Mol file: 994-28-5.mol

Synonyms:Triethylgermanium chloride;994-28-5;Chlorotriethylgermane;Triethylchlorogermane;chloro(triethyl)germane;triethylchlorogermene;triethylgermyl chloride;CCRIS 2650;EINECS 213-614-0;NSC 158926;TRIETHYLGERMANIUMCHLORIDE;DTXSID3049382;UNII-3M5C1118J0;3M5C1118J0;NSC-158926;MFCD00013591;NSC158926;C6H15ClGe;Germane, chlorotriethyl-;Chlorotriethylgermane, 96%;C6-H15-Cl-Ge;SCHEMBL301642;DTXCID0029341;Tox21_202954;SILVERTRIFLUOROMETHANESULFONATE;AKOS015838470;NCGC00260500-01;CAS-994-28-5;LS-188222;FT-0713798;T1160;D92460;Q27257622

Chemical Property of Triethylgermanium chloride

Chemical Property:

• Appearance/Colour: colorless clear liquid.
• Melting Point: <-50 °C
• Refractive Index: n20/D 1.459(lit.)
• Boiling Point: 176 °C at 760 mmHg
• Flash Point: 43.2 °C
• PSA: 0.00000
• Density: 1.175 g/cm³
• LogP: 3.23040
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 196.0074059
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

Triethylchlorogermane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[Ge](CC)(CC)Cl
• Uses: Triethylgermanium chloride is used as an organic intermediate.

Technology Process of Triethylgermanium chloride

There total 47 articles about Triethylgermanium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Triethylgerman (1188-14-3) + vanadium(V) oxychloride (7727-18-6) → vanadyl(IV) chloride + vanadium(III) oxide chloride + hydrogen (1333-74-0) + triethylchlorogermane (994-28-5)

Guidance literature:

In neat (no solvent); heating reagents;;

DOI:10.1021/ja01559a022 DOI:10.1021/ja01575a023

Reference yield: 80.0%

triethyl germanium (1+); triethylgermanylmercapto acetate (872304-62-6) → mercapto-acetic acid ; mercury (II)-compound + triethylchlorogermane (994-28-5)

Guidance literature:

With mercury dichloride; at heating to reflux;;

Reference yield: 76.0%

Triethylgerman (1188-14-3) + copper dichloride → triethylchlorogermane (994-28-5)

Guidance literature:

copper(l) iodide; In diethyl ether; hydrogermane mixed with 2 equiv. of CuCl2 and CuI in ether under room temp. for 3 h; solvent evapd., distilled under reduced pressure;

DOI:10.1246/cl.2001.886

upstream raw materials:

Bromotriethylgermanium

benzyl chloride

triethyl(iodo)germane

Triethylgerman

Downstream raw materials:

triethylgermylpentafluorobenzene

(N(C₂H₅)2)3PClBr

triethylgermyl 2-benzoylbenzoate

(triethylgermyl)(triphenylgermyl)oxide

Refernces

• 1、 Boukherroub, Rabah,Manuel, Georges. "Syntheses de 3-silyl et de 3-germyl 1-sila et 1-germacyclopent-3-enes". . p. 155 - 162. Retrieved 1993.
• 2、 Vyazankin et al.. "". . . Retrieved 1972.
• 3、 Stepovik,Gulenova,Martynova,Skvortsov,Cherkasov. "Reaction of organoelement hydrides R3EH (E = Si, Ge) with metal tert-butylate (M = Al, Ti)-tert-butyl hydroperoxide oxidative systems". . p. 1098 - 1107. Retrieved 2007/10/03.
• 4、 Nosov,Koroteev,Egorov. "Redox reactions of GeII and SnII dihalides with triethylsilane and triethylgermane". . p. 1325 - 1328. Retrieved 2007/10/03.