Cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl-

Base Information

• Chemical Name: Cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl-
• CAS No.: 14576-08-0
• Molecular Formula: C11H20O
• Molecular Weight: 168.279
• Hs Code.: 2909209000
• European Community (EC) Number: 238-620-0
• NSC Number: 52566
• UNII: J85U4SDI1I
• DSSTox Substance ID: DTXSID9041819
• Nikkaji Number: J138.274H
• Wikidata: Q27281335
• Mol file: 14576-08-0.mol

Synonyms:14576-08-0;Cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl-;Terpinyl methyl ether;4-(2-methoxypropan-2-yl)-1-methylcyclohexene;4-(1-Methoxy-1-methylethyl)-1-methylcyclohexene;4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene;Methyl alpha-terpinyl ether;8-Methoxy-p-menth-1-ene;UNII-J85U4SDI1I;J85U4SDI1I;alpha-Terpineol, methyl ether;EINECS 238-620-0;NSC 52566;NSC-52566;AI3-32544;ORANGEFLOWERETHER;SCHEMBL197147;DTXSID9041819;CHEBI:167340;NSC52566;.ALPHA.-TERPINYL METHYL ETHER;METHYL .ALPHA.-TERPINYL ETHER;AKOS006273051;.ALPHA.-TERPINEOL, METHYL ETHER;ETHER, P-MENTH-1-EN-8-YL METHYL;J138.274H;METHYL(P-MENTHA-1-ENE-8-YL) ETHER;1-methyl-4-[a-methoxyisopropyl] -1-cyclohexene;4-(2-METHOXY-2-PROPANYL)-1-METHYLCYCLOHEXENE;Q27281335;1-METHYL-4-(1-METHOXY-1-METHYLETHYL)-1-CYCLOHEXENE;4 - (1 - methoxy - 1 - methylethyl) - 1 - methylcyclohexene;METHYL(2-(4-METHYL-3-CYCLOHEXENE-1-YL)PROPANE)-2-YL ETHER;METHYL(1-(1-METHYL-1-CYCLOHEXENE-4-YL)-1-METHYLETHYL) ETHER

Chemical Property of Cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl-

Chemical Property:

• Vapor Pressure: 0.458mmHg at 25°C
• Refractive Index: 1.457
• Boiling Point: 200.5 °C at 760 mmHg
• Flash Point: 61.4 °C
• PSA: 9.23000
• Density: 0.884 g/cm³
• LogP: 3.15780
• Water Solubility.: 85mg/L at 23℃
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 168.151415257
• Heavy Atom Count: 12
• Complexity: 179

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CCC(CC1)C(C)(C)OC

Technology Process of Cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl-

There total 35 articles about Cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methanol (67-56-1) + α-terpinyl chloride (39864-10-3) → 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene (14576-08-0)

Guidance literature:

With zinc(II) oxide; for 6h; Heating;

DOI:10.1016/0040-4020(82)80261-5

Reference yield: 80.0%

methanol (67-56-1) + limonene. (138-86-3,555-08-8,8022-90-0,9003-73-0,95327-98-3) → 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene (14576-08-0)

Guidance literature:

With iron(III) chloride; In dichloromethane; at 0 - 20 ℃; for 1.2h;

DOI:10.1016/j.tetlet.2009.07.057

Reference yield: 80.0%

methanol (67-56-1) + Beta-pinene (177698-19-0,25719-60-2) → 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene (14576-08-0)

Guidance literature:

With iron(III) chloride; In dichloromethane; at 0 - 20 ℃; for 1h;

DOI:10.1016/j.tetlet.2009.07.057

upstream raw materials:

methanol

Geraniol

limonene.

(+)-β-citronellene

Downstream raw materials:

8-methoxy-p-menthane

Refernces

• 1、 Lemechko, Pierre,Grau, Fanny,Antoniotti, Sylvain,Du?ach, Elisabet. "Hydroalkoxylation of non-activated olefins catalysed by Lewis superacids in alcoholic solvents: an eco-friendly reaction". . p. 5731 - 5734. Retrieved 2007.
• 2、 Polo, Henrique Priori,Lopes, Neide Paloma Goncalves,da Silva, Márcio José. "Exploring the Keggin-Type Heteropolyacid-Catalyzed Reaction Pathways of the Β-Pinene with Alkyl Alcohols". . p. 2844 - 2853. Retrieved 2019/05/28.
• 3、 Li, Ren-Jie,Xu, Jian-He,Yin, Yue-Cai,Wirth, Nicolas,Ren, Jiang-Meng,Zeng, Bu-Bing,Yu, Hui-Lei. "Rapid probing of the reactivity of P450 monooxygenases from the CYP116B subfamily using a substrate-based method". supporting information. p. 8928 - 8934. Retrieved 2016/10/13.