METHYL PHENYL CARBONATE

Base Information

• Chemical Name: METHYL PHENYL CARBONATE
• CAS No.: 13509-27-8
• Molecular Formula: C8H8O3
• Molecular Weight: 152.15
• Hs Code.: 2920909090
• Mol file: 13509-27-8.mol

Synonyms:Methylphenyl carbonate;Phenyl methoxyformate;Phenyl methyl carbonate;

Chemical Property of METHYL PHENYL CARBONATE

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 0.124mmHg at 25°C
• Melting Point: 147-151 °C
• Refractive Index: 1.4985
• Boiling Point: 218.7 °C at 760 mmHg
• Flash Point: 97.1 °C
• PSA: 35.53000
• Density: 1.14 g/cm³
• LogP: 1.83180
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Methylphenylcarbonate 97% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL PHENYL CARBONATE

There total 43 articles about METHYL PHENYL CARBONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

carbonic acid dimethyl ester (616-38-6) + phenol (108-95-2,27073-41-2) → methyl phenyl carbonate (13509-27-8)

Guidance literature:

lead (II) phenoxide; at 220 ℃; for 500 - 6000h; under 6750.68 Torr; Product distribution / selectivity; Heating / reflux;

Reference yield: 88.0%

methanol (67-56-1) + phenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate (1202680-24-7) → methyl phenyl carbonate (13509-27-8)

Guidance literature:

With aluminum (III) chloride; In toluene; at 20 ℃; for 1h;

DOI:10.5012/bkcs.2014.35.9.2758

Reference yield: 86.3%

carbonic acid dimethyl ester (616-38-6) + phenol (108-95-2,27073-41-2) → methyl phenyl carbonate (13509-27-8) + methoxybenzene (100-66-3)

Guidance literature:

With KCl supported on CaO; at 220 ℃; for 10h; Reagent/catalyst; Temperature; Catalytic behavior; Autoclave;

DOI:10.1134/S0023158421040145

upstream raw materials:

bis(phenyl) carbonate

methanol

methyl 1,1,1-trichloromethyl carbonate

sodium phenoxide

Downstream raw materials:

p-nitrophenyl methyl carbonate

methoxybenzene

carbonic acid dimethyl ester

methyl (3-amino-4-methylphenyl)carbamate

Refernces

• 1、 Guillot-Edelheit,G. et al.. "-". . p. 1123 - 1127. Retrieved 1979.
• 2、 Castro, Enrique A.,Freudenberg, Margarita. "Bronsted Plots in the Reactions of 2,4-Dinitrophenyl Acetate and Methyl Phenyl Carbonate with Substituted Pyridines". . p. 906 - 910. Retrieved 1980.
• 3、 -. "Synthetic method of carbonic ester compound". Paragraph 0032-0038. . Retrieved 2021/06/06.
• 4、 Saini, Sandhya,Gour, Nand Kishor,Khan, Shafiur Rehman,Deka, Ramesh Chandra,Jain, Suman L.. "Light-induced synthesis of unsymmetrical organic carbonates from alcohols, methanol and CO2under ambient conditions". supporting information. p. 12800 - 12803. Retrieved 2021/12/13.