ruthenocene carboxylaldheyde

Base Information

• Chemical Name: ruthenocene carboxylaldheyde
• CAS No.: 66507-25-3
• Molecular Formula: C₁₁H₁₀ORu
• Molecular Weight: 259.27
• Mol file: 66507-25-3.mol

Synonyms:ruthenocene carboxylaldheyde

Chemical Property of ruthenocene carboxylaldheyde

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of ruthenocene carboxylaldheyde

There total 1 articles about ruthenocene carboxylaldheyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(η5-cyclopentadienyl)ruthenium (1287-13-4) + ferrocene (102-54-5,55404-68-7) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → ferrocenecarboxaldehyde (12093-10-6) + 1,1'-ferrocenyldicarboxaldehyde (1271-48-3) + ruthenocene carboxylaldheyde (66507-25-3) + ruthenocene-1,1'-dicarboxaldehyde

Guidance literature:

With tert.-butyl lithium; In tetrahydrofuran; N2-atmosphere; dropwise addn. of t-BuLi to mixt. of metallocenes at -74 to -70°C, stirring at -30°C for 3 h, addn. of excess DMF, warming to -10°C; water addn., solvent removal (reduced pressure), extn. into CH2Cl2, drying (MgSO4), chromy. (SiO2, hexane, then CH2Cl2, then CH2Cl2/Et2O=1:1);

DOI:10.1016/0022-328X(95)05914-B

Reference yield: 99.0%

ruthenocene carboxylaldheyde (66507-25-3) + L-Phenylalaninol (3182-95-4) → (C5H5)Ru(C5H4C10H12NO)*0.25H2O

Guidance literature:

With potassium carbonate; In neat (no solvent); stirring (darkness); hexane and K2CO3 addn., filtn., concn.; elem. anal.;

DOI:10.1007/BF02495266

Reference yield: 99.0%

ruthenocene carboxylaldheyde (66507-25-3) + (1S,2R)-2-amino-1-phenylpropane-1,3-diol (119364-52-2) → (C5H5)Ru(C5H4C10H12NO2)*0.15CHCl3

Guidance literature:

With potassium carbonate; In neat (no solvent); stirring (darkness); hexane/CHCl2 and K2CO3 addn., filtn., concn.; elem. anal.;

DOI:10.1007/BF02495266

upstream raw materials:

bis(η⁵-cyclopentadienyl)ruthenium

ferrocene

N,N-dimethyl-formamide

Downstream raw materials:

5'-(phenyl)-2'-ruthenocenylpyrrolidino[3',4':1,2] [60]fullerene

N-(ruthenocenylmethylene)-4-nitroaniline

ruthenocenecarboxaldehyde 4-nitrophenylhydrazone

Refernces