2,4-DINITRO-N,N-DIETHYLANILINE

Base Information

• Chemical Name: 2,4-DINITRO-N,N-DIETHYLANILINE
• CAS No.: 837-64-9
• Molecular Formula: C10H13 N3 O4
• Molecular Weight: 239.231
• Mol file: 837-64-9.mol

Synonyms:Aniline,N,N-diethyl-2,4-dinitro- (6CI,7CI,8CI); 2,4-Dinitro-N,N-diethylaniline;N,N-Diethyl-2,4-dinitroaniline; N,N-Diethyl-2,4-dinitrobenzenamine; NSC 42401

Chemical Property of 2,4-DINITRO-N,N-DIETHYLANILINE

Chemical Property:

• Vapor Pressure: 1.05E-05mmHg at 25°C
• Boiling Point: 371.1°C at 760 mmHg
• Flash Point: 178.3°C
• PSA: 94.88000
• Density: 1.299g/cm³
• LogP: 3.39560

Purity/Quality:

99% ^*data from raw suppliers

N,N-DIETHYL-2,4-DINITROANILINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 2,4-DINITRO-N,N-DIETHYLANILINE

There total 25 articles about 2,4-DINITRO-N,N-DIETHYLANILINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diethylamine (109-89-7) + 1-chloro-2,4-dinitro-benzene (97-00-7) → N,N-diethyl-2,4-dinitroaniline (837-64-9)

Guidance literature:

In ethanol; water; at 60 ℃; for 6h;

Reference yield: 92.0%

2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) + diethylamine (109-89-7) → N,N-diethyl-2,4-dinitroaniline (837-64-9)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 50 ℃; for 3h;

DOI:10.1071/CH9950997

Reference yield: 84.0%

2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) + triethylamine (121-44-8) → N,N-diethyl-2,4-dinitroaniline (837-64-9)

Guidance literature:

With tris[2-phenylpyridinato-C₂,N]iridium(III); N-ethyl-N,N-diisopropylamine; In dimethyl sulfoxide; at 20 ℃; for 40h; Reagent/catalyst; Solvent; Irradiation;

DOI:10.3390/molecules26113323

upstream raw materials:

4-(diethylamino)benzoic acid

2,4-dinitrobromobenzene

diethylamine

1-chloro-2,4-dinitro-benzene

Downstream raw materials:

2,4-dinitro-N-ethylaniline

N-ethyl-2,4-dinitro-N-nitroso-aniline

2,4-Dinitrophenol

diethylamine

Refernces

• 1、 Manne, Srinivasa Rao,Chandra, Jyoti,Mandal, Bhubaneswar. "Synthesis of o-Nitroarylamines via Ipso Nucleophilic Substitution of Sulfonic Acids". supporting information. p. 636 - 639. Retrieved 2019/01/21.
• 2、 Valvi, Arun,Tiwari, Shraeddha. "“Zero VOC” Synthetic Strategy – Aromatic Amination Reactions in Deep Eutectic Solvents". . p. 4933 - 4939. Retrieved 2018/09/11.