Sodium mesitylenesulfonate

Base Information

• Chemical Name: Sodium mesitylenesulfonate
• CAS No.: 6148-75-0
• Molecular Formula: C9H11NaO3S
• Molecular Weight: 222.24
• Hs Code.: 2904100000
• Mol file: 6148-75-0.mol

Synonyms:2-Mesitylenesulfonicacid, sodium salt (8CI);Benzenesulfonic acid, 2,4,6-trimethyl-, sodium salt (9CI);Sodium 2,4,6-trimethylbenzenesulfonate;Sodium 2-mesitylenesulfonate;Sodiummesitylenesulfonate;

Chemical Property of Sodium mesitylenesulfonate

Chemical Property:

• Melting Point: >300°C
• PSA: 65.58000
• LogP: 2.59670
• Water Solubility.: very faint turbidity

Purity/Quality:

99% ^*data from raw suppliers

Sodium Mesitylenesulfonate >98.0%(HPLC)(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Sodium mesitylenesulfonate

There total 2 articles about Sodium mesitylenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,5-trimethyl-benzene (108-67-8) → 2,4,6-trimethylbenzenesulfonate sodium salt (6148-75-0)

Guidance literature:

With chlorosulfonic acid; sodium hydroxide; In dichloromethane; for 10h; Ambient temperature;

DOI:10.1246/bcsj.66.2590

Reference yield:

bis(2,4,6-trimethylphenyl)iodonium tetrafluoroborate → 2,4,6-trimethylbenzenesulfonate sodium salt (6148-75-0)

Guidance literature:

With iron(III) chloride; sodium hydroxymethanesulfinate dihydrate; In N,N-dimethyl-formamide; acetonitrile; at 20 ℃; for 0.333333h;

DOI:10.1039/c5cc09830k

Reference yield: 94.0%

2,4,6-trimethylbenzenesulfonate sodium salt (6148-75-0) → 2-mesitylenesulphonyl chloride (773-64-8)

Guidance literature:

With 1,3,5-trichloro-2,4,6-triazine; 18-crown-6 ether; In acetone; for 20h; Heating;

DOI:10.1016/S0040-4039(02)02853-8

upstream raw materials:

1,3,5-trimethyl-benzene

Downstream raw materials:

2-mesitylenesulphonyl chloride

tetrabutylphosphonium 2,4,6-trimethylbenzenesulfonate

mesitylenecarboxylic acid

2,4,6-trimethylbenzene-1-sulfonyl fluoride

Refernces

• 1、 Iwamoto, Hidetoshi,Kobayashi, Hiroshi,Murer, Pius,Sonoda, Takaaki,Zollinger, Heinrich. "Mechanism of Azo Coupling Reactions: Part XXXVI. The Relationship between the Structure and the Catalytic Activity of Anionic Phase-Transfer Catalysts in Azo Coupling Reactions". . p. 2590 - 2602. Retrieved 2007/10/02.