9-chloro-m-carborane

Base Information

• Chemical Name: 9-chloro-m-carborane
• CAS No.: 17819-85-1
• Molecular Formula: C₂H₁₁B₁₀Cl
• Molecular Weight: 178.672
• Mol file: 17819-85-1.mol

Synonyms:9-chloro-m-carborane

Chemical Property of 9-chloro-m-carborane

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-chloro-m-carborane

There total 16 articles about 9-chloro-m-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate (99506-45-3) + sodium chloride (7647-14-5) → 9-iodo-m-carborane (17157-02-7) + 9-chloro-m-carborane (17819-85-1) + para-iodoanisole (696-62-8) + methoxybenzene (100-66-3)

Guidance literature:

In chloroform; water; mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;

Reference yield: 100.0%

4-fluorophenyl(m-carboran-9-yl)iodonium tetrafluoroborate (99506-39-5) + sodium chloride (7647-14-5) → fluorobenzene (462-06-6) + 9-iodo-m-carborane (17157-02-7) + 9-chloro-m-carborane (17819-85-1) + 4-fluoro-1-iodobenzene (352-34-1)

Guidance literature:

In chloroform; water; mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;

Reference yield: 100.0%

3-nitrophenyl(m-carboran-9-yl)iodonium tetrafluoroborate (99506-41-9) + sodium chloride (7647-14-5) → m-iodonitrobenzene (645-00-1) + 9-iodo-m-carborane (17157-02-7) + 9-chloro-m-carborane (17819-85-1) + nitrobenzene (98-95-3,26969-40-4)

Guidance literature:

In chloroform; water; mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;

upstream raw materials:

bis(1,7-dicarba-closo-dodecaboran⁽¹²⁾-yl-1)mercury

Trichloroethylene

(1,7-dicarba-closo-dodecaboran⁽¹²⁾-yl-1)mercury chloride

phenyl(m-carboran-9-yl)bromonium tetrafluoroborate

Downstream raw materials:

3-amino-1,2-dicarbaborane

1,2-dicarba-closo-dodecaborane⁽¹²⁾

1,7-dicarba-closo-dodecaborane⁽¹²⁾

9-Cl-o-HCB₁₀H₉CH

Refernces

• 1、 Grushin, Vladimir V.,Demkina, Iraida I.,Tolstaya, Tat'yana P.. "Reactions of aryl(B-carboranyl)iodonium cations with the fluoride anion. Synthesis of icosahedral o-carboran-9-yl, m-carboran-9-yl, and p-carboran-2-yl fluorides". . p. 4860 - 4863. Retrieved 2008/10/08.