Cyclopropyl methyl ether

Base Information

• Chemical Name: Cyclopropyl methyl ether
• CAS No.: 540-47-6
• Molecular Formula: C4H8 O
• Molecular Weight: 72.1069
• Hs Code.: 2909209000
• UNII: 5621193HIQ
• DSSTox Substance ID: DTXSID30202313
• Nikkaji Number: J6.387H
• Wikidata: Q27261357
• Mol file: 540-47-6.mol

Synonyms:Cyclopropyl methyl ether;Methoxycyclopropane;Cyprome ether;Cyclopropane, methoxy-;540-47-6;1-Methoxycyclopropane;Methyl cyclopropyl ether;Ether, cyclopropyl methyl;BRN 1918444;UNII-5621193HIQ;5621193HIQ;cyclopropylmethyl ether;DTXSID30202313;CYCLOPROPYL METHYL ETHER [MI];LS-67811;EN300-7570918;Q27261357

Chemical Property of Cyclopropyl methyl ether

Chemical Property:

• Vapor Pressure: 372mmHg at 25°C
• Melting Point: -119°
• Refractive Index: nD20 1.3802
• Boiling Point: 44.7°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.87g/cm³
• LogP: 0.79520
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 72.057514874
• Heavy Atom Count: 5
• Complexity: 30.6

Purity/Quality:

99%, ^*data from raw suppliers

CYCLOPROPYL METHYL ETHER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC1CC1
• Uses: Insecticide.

Technology Process of Cyclopropyl methyl ether

There total 19 articles about Cyclopropyl methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oxirane (75-21-8,99932-75-9) + methanol (67-56-1) + N-nitroso-N-cyclopropylurea (10575-90-3) → methylallylether (627-40-7) + monoethylene glycol methyl allyl ether (18854-48-3,27252-80-8) + cyclopropyl methyl ether (540-47-6) + 3-<2-(2-Methoxyethoxy)ethoxy>propen (13752-97-1,27252-80-8) + (2-Methoxyethoxy)cyclopropan

Guidance literature:

With sodium hydrogencarbonate; Product distribution; Ambient temperature; var. conc., further reactions with NaOCH₃, oxetane, tetrahydrofuran;

Reference yield:

trimethyl (3-methoxypropyl)tin (80426-24-0) → tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + methyl propyl ether (557-17-5) + cyclopropyl methyl ether (540-47-6)

Guidance literature:

With benzophenone; In benzene; at 22 ℃; for 72h; Yield given. Yields of byproduct given; Irradiation; further reagents (PhCOMe, (t-BuO)2, FeCl₃);

DOI:10.1021/ja00415a043

Reference yield:

N-nitroso-N-cyclopropylurea (10575-90-3) → Cyclopropyl methyl ketone (765-43-5) + 1,2-propanediene (463-49-0) + methylallylether (627-40-7) + cyclopropyl methyl ether (540-47-6)

Guidance literature:

With sodium methylate; acetaldehyde; In methanol; at 20 ℃; for 3h; Further byproducts given;

upstream raw materials:

oxirane

methanol

N-nitroso-N-cyclopropylurea

trimethylene oxide

Downstream raw materials:

methane

methyl (Z)-prop-1-enyl ether

(E)-1-Methoxy-1-propen

methylallylether

Refernces

• 1、 Kirmse, Wolfgang,Rode, Jutta,Rode, Klaus. "Deamination Reactions, 44. Decomposition of 1-Alkylcyclopropanediazonium Ions". . p. 3672 - 3693. Retrieved 2007/10/02.
• 2、 Davis, Dennis D.,Ahmed, Fahim U.. "Homolytic Substitution at Carbon: 1,3- and 1,5-Ring Closures in Organotin-Substituted Radicals". . p. 7653 - 7654. Retrieved 2007/10/02.