9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure

Base Information

• Chemical Name: 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure
• CAS No.: 58186-07-5
• Molecular Formula: C₁₈H₂₆O₆
• Molecular Weight: 338.401
• Mol file: 58186-07-5.mol

Synonyms:9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure

Chemical Property of 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure

There total 4 articles about 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

1,10-decanedioic acid (111-20-6,26776-29-4) + 2,3-Dimethoxy-5-methyl-1,4-benzoquinone (605-94-7) → 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure (58186-07-5)

Guidance literature:

With ammonium peroxydisulfate; silver nitrate; In water; acetonitrile; for 0.166667h; Heating;

Reference yield:

2,3-dimethoxy-5-methyl-6-(8'-ethoxycarbonyloctyl)-1,4-benzoquinone (58186-06-4) → 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure (58186-07-5)

Guidance literature:

With potassium hydroxide; iron(III) chloride; In diethyl ether;

Reference yield:

9-(2,5-Dihydroxy-3,4-dimethoxy-6-methyl-phenyl)-nonanoic acid ethyl ester → 9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonansaeure (58186-07-5)

Guidance literature:

With potassium hydroxide; sodium dithionite; iron(III) chloride; Yield given. Multistep reaction; 1.) 50 deg C, 2.5 h;

DOI:10.1248/cpb.30.2797

upstream raw materials:

2,3-dimethoxy-5-methyl-6-(8'-ethoxycarbonyloctyl)-1,4-benzoquinone

1,10-decanedioic acid

2,3-Dimethoxy-5-methyl-1,4-benzoquinone

bis-(9-ethoxycarbonyl-nonanoyl)-peroxide

Downstream raw materials:

9-(5,6-Dimethoxy-3-methyl-1,4-benzochinon-2-yl)nonanal

Refernces

• 1、 Okamoto,Watanabe,Kawada,Goto,Ashida,Oda,Yajima,Imada,Morimoto. "Synthesis of quinones having carboxy- and hydroxy-alkyl side chains, and their effects on rat-liver lysosomal membrane.". . p. 2797 - 2819. Retrieved 2007/10/02.