2-Methyl-3(2-furyl)acrolein

Base Information Edit

Chemical Name:2-Methyl-3(2-furyl)acrolein
CAS No.:874-66-8
Molecular Formula:C8H8 O2
Molecular Weight:136.15
Hs Code.:2932190090
European Community (EC) Number:212-866-9
UNII:65U4YZ14MX
Wikidata:Q27263911
Mol file:874-66-8.mol

Synonyms:FEMA No. 2704;Furfurylidene-2-propanal;2-methyl-3(2-furyl)acrolein;2-Methyl-3-(2-furyl)-2-propenal;cinnamon acrolein;2-Furanacrolein, alpha-methyl-;2-PROPENAL, 3-(2-FURANYL)-2-METHYL-;EINECS 212-866-9;874-66-8;3-Furanacrolein, 2-methyl-;65U4YZ14MX;alpha -Methylfurylacrolein;SCHEMBL1532601;AKOS000268597;.ALPHA.-METHYL-2-FURANACROLEIN;2-FURANACROLEIN, .ALPHA.-METHYL-;LS-70042;METHYL-3-(2-FURYL)ACROLEIN, 2-;3-(2-FURYL)-2-METHYLPROP-2-ENAL;2-METHYL-3(2-FURYL)ACROLEIN [FHFI];2-METHYL-3-(.ALPHA.-FURYL)PROPENAL-2;3-(2-(FURANYL)-2-METHYL-2-PROPENAL;.ALPHA.-METHYL-.BETA.-(2-FURYL)ACROLEIN;Q27263911

Suppliers and Price of 2-Methyl-3(2-furyl)acrolein

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-METHYL-3-(2-FURYL)PROPENAL 95.00%
5MG
$ 499.15

Alfa Aesar
2-Methyl-3-(2-furyl)propenal, 97%
250g
$ 608.00

Alfa Aesar
2-Methyl-3-(2-furyl)propenal, 97%
50g
$ 156.00

Alfa Aesar
2-Methyl-3-(2-furyl)propenal, 97%
10g
$ 42.50

Total 24 raw suppliers

Chemical Property of 2-Methyl-3(2-furyl)acrolein Edit

Chemical Property:

Appearance/Colour:colorless to yellow liquid
Vapor Pressure:0.113mmHg at 25°C
Refractive Index:1.6140
Boiling Point:280-281°C
Flash Point:>100°C
PSA：30.21000
Density:1,097 g/cm³
LogP:1.88180
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:136.052429494
Heavy Atom Count:10
Complexity:149

Purity/Quality:

99% ^*data from raw suppliers

2-METHYL-3-(2-FURYL)PROPENAL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): R22:Harmful if swallowed.; R36/37/38:Irritating to eyes, respiratory system and skin.;
Hazard Codes:R22:Harmful if swallowed.; R36/37/38:Irritating to eyes, respiratory system and skin.;
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CC1=CC=CO1)C=O
Isomeric SMILES:C/C(=C/C1=CC=CO1)/C=O

Technology Process of 2-Methyl-3(2-furyl)acrolein

There total 15 articles about 2-Methyl-3(2-furyl)acrolein which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 147227-25-6
α,α-bis(trimethylsilyl)-tert-butylpropionaldimine

: 98-01-1
furfural

: (Z)-3-furan-2-yl-2-methylpropenal

: 874-66-8,108576-21-2
(E)-3-(furan-2-yl)-2-methylacrylaldehyde

Guidance literature:: α,α-bis(trimethylsilyl)-tert-butylpropionaldimine; furfural; With zinc dibromide; In tetrahydrofuran; at 20 ℃; for 8h;

With water; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1016/j.jorganchem.2006.03.015

Reference yield: 82.0%

: 98-01-1
furfural

: 123-38-6
propionaldehyde

: 874-66-8,108576-21-2
(E)-3-(furan-2-yl)-2-methylacrylaldehyde

Guidance literature:: With potassium hydroxide; tert-butylammonium hexafluorophosphate(V); In benzene; at 20 ℃; for 3h;
DOI:10.1002/ejoc.200400880

Reference yield: 71.0%

: 98-01-1
furfural

: 123-38-6
propionaldehyde

: 874-66-8
2-methyl-3-(2-furyl)-propenal

Guidance literature:: With Mg-Al hydrotalcite; In N,N-dimethyl-formamide; at 99.84 ℃; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c3cy00980g