Phosphoric acid, 2,2-dichlorovinyl diisopropyl ester

Base Information

• Chemical Name: Phosphoric acid, 2,2-dichlorovinyl diisopropyl ester
• CAS No.: 71-96-5
• Molecular Formula: C8H15 Cl2 O4 P
• Molecular Weight: 277.084
• NSC Number: 133042
• DSSTox Substance ID: DTXSID90221222
• Nikkaji Number: J92.213G
• Mol file: 71-96-5.mol

Synonyms:Phosphoric acid, 2,2-dichlorovinyl diisopropyl ester;71-96-5;NSC 133042;2,2-Dichlorovinyl diisopropyl phosphate;BRN 1712549;Diisopropyl dichlorvinyl phosphat [German];AI3-20755;Diisopropyl dichlorvinyl phosphat;Phosphoric acid, 2,2-dichloroethenyl bis(1-methylethyl) ester;C8H15Cl2O4P;dii-propyldichlorvinylphosphat;SCHEMBL5157514;DTXSID90221222;NSC133042;NSC-133042;(2,2-Dichlorovinyl)diisopropyl=phosphate;LS-107679

Chemical Property of Phosphoric acid, 2,2-dichlorovinyl diisopropyl ester

Chemical Property:

• Vapor Pressure: 0.038mmHg at 25°C
• Boiling Point: 248.6°C at 760 mmHg
• Flash Point: 107.5°C
• Density: 1.255g/cm³
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 276.0085013
• Heavy Atom Count: 15
• Complexity: 247

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)OP(=O)(OC=C(Cl)Cl)OC(C)C

Technology Process of Phosphoric acid, 2,2-dichlorovinyl diisopropyl ester

There total 5 articles about Phosphoric acid, 2,2-dichlorovinyl diisopropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2,2,2-trichloro-1-hydroxy-ethyl)-phosphonic acid diisopropyl ester (996-42-9) → phosphoric acid 2,2-dichloro-vinyl ester diisopropyl ester (71-96-5)

Guidance literature:

With sodium hydroxide;

DOI:10.1021/ja01614a019

Reference yield:

triisopropyl phosphite (116-17-6) + chloral (75-87-6) → phosphoric acid 2,2-dichloro-vinyl ester diisopropyl ester (71-96-5)

Guidance literature:

DOI:10.1021/jo01263a072 DOI:10.1021/ja01614a019 DOI:10.1021/ja01615a061

Reference yield:

O-butyl-P-methyl-phosphonothioic O,O'-diisopropyl-phosphorous anhydride (51090-76-7) + chloral (75-87-6) → phosphoric acid 2,2-dichloro-vinyl ester diisopropyl ester (71-96-5)

Guidance literature:

In diethyl ether;

upstream raw materials:

(2,2,2-trichloro-1-hydroxy-ethyl)-phosphonic acid diisopropyl ester

triisopropyl phosphite

chloral

O-butyl-P-methyl-phosphonothioic O,O'-diisopropyl-phosphorous anhydride

Downstream raw materials:

phosphoric acid diisopropyl ester-(1,2,2,2-tetrachloro-ethyl ester)

2,2-dichloroacetaldehyde

Refernces

• 1、 Krutikov, V. I.,Naidenov, A. V.,Palagina, T. V.,Lebedev, V. B.,Lavrent'ev, A. N.. "THE COMPLEX COURSE OF THE REACTION BETWEEN PHOSPHITE AND PHOSPHONITE ESTERS AND CHLORAL HYDRATE". . p. 1839 - 1841. Retrieved 2007/10/02.