triphenylgermanium fluoride

Base Information

• Chemical Name: triphenylgermanium fluoride
• CAS No.: 379-47-5
• Molecular Formula: C₁₈H₁₅FGe
• Molecular Weight: 322.906
• Mol file: 379-47-5.mol

Synonyms:triphenylgermanium fluoride

Chemical Property of triphenylgermanium fluoride

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triphenylgermanium fluoride

There total 11 articles about triphenylgermanium fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + OsH(C5H5)C2C6H5(Ge(C6H5)3)P(C3H7)3 → [OsH(η5-C5H5)(CCH2Ph)(CH(CH3)2)](BF4) (438588-75-1) + triphenylgermanium fluoride (379-47-5)

Guidance literature:

In diethyl ether; HBF4*OEt2 was added to soln. of Os-complex in Et2O in air; decanted, washed with Et2O;

DOI:10.1021/om011077e

Reference yield: 71.0%

chlorotriphenylgermane (1626-24-0) + trimethyltin fluoride (420-60-0) → triphenylgermanium fluoride (379-47-5)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In tetrahydrofuran; at 100 ℃; for 18h; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1039/d1cc01392k

Reference yield: 70.0%

triphenylgermane (2816-43-5) + tetrabutylammonium tetrafluoroborate (429-42-5) → triphenylgermanium fluoride (379-47-5) + bis(triphenylgermyl)oxide (2181-40-0)

Guidance literature:

In acetonitrile; Electrolysis; const.current electrolysis with Pt electrodes, c.d. 0.17 mA/cm**2; analyzed with GC-MS and HPLC;

DOI:10.1246/bcsj.64.1381

upstream raw materials:

bis(triphenylgermyl)mercury

difluorogermylene

triphenylgermane

tetrabutylammonium tetrafluoroborate

Downstream raw materials:

tetraphenylgermane

Triphenylgermanol

((C₆H₅)3Ge)3N

Bis-(triphenylgermyl)-amin

Refernces

• 1、 Kameo, Hajime,Mushiake, Akihiro,Isasa, Tomohito,Matsuzaka, Hiroyuki,Bourissou, Didier. "Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge-F bond activation". supporting information. p. 5004 - 5007. Retrieved 2021/05/28.
• 2、 Okano, Mitsutoshi,Mochida, Kunio. "Electrochemical Halogenation of Trisubstituted Germanes and Silanes". . p. 1381 - 1382. Retrieved 2007/10/02.