1-azidonaphthalene-5-sulfonate

Base Information

• Chemical Name: 1-azidonaphthalene-5-sulfonate
• CAS No.: 73105-93-8
• Molecular Formula: C₁₀H₇N₃O₃S
• Molecular Weight: 249.25
• Mol file: 73105-93-8.mol

Synonyms:1-Azidonaphthalene-5-sulfonicacid; 5-Azido-1-naphthalenesulfonic acid

Chemical Property of 1-azidonaphthalene-5-sulfonate

Chemical Property:

• PSA: 112.50000
• LogP: 3.56186

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-azidonaphthalene-5-sulfonate

There total 2 articles about 1-azidonaphthalene-5-sulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

1-aminonaphthalene-5-sulfonic acid (84-89-9) → 1-Azido-5-naphtalene sulfonate (73105-93-8)

Guidance literature:

1-aminonaphthalene-5-sulfonic acid; With sulfuric acid; sodium nitrite; at 0 ℃; for 0.75h;

With sodium azide; In water; at 4 ℃; for 8h;

DOI:10.1016/j.bmcl.2008.04.031

Reference yield:

→ 1-Azido-5-naphtalene sulfonate (73105-93-8)

Guidance literature:

5-Aminonaphthalin-1-sulfonsaeure, NaNO2;

DOI:10.1021/bi00576a019

Reference yield: 44.0%

1-Azido-5-naphtalene sulfonate (73105-93-8) → 1-azido-5-naphthalene sulfonyl chloride (73936-73-9)

Guidance literature:

With phosphorus pentachloride; at 60 - 80 ℃;

upstream raw materials:

1-aminonaphthalene-5-sulfonic acid

Downstream raw materials:

1-azido-5-naphthalene sulfonyl chloride

Refernces

• 1、 Muramoto, Koji,Kamiya, Hisao. "Preparation and Characterization of a Cleavable Photoacivable Heterobifunctional Fluorescent Reagent". . p. 547 - 554. Retrieved 2007/10/02.