C₁₄H₁₃NO₂S

Base Information

• Chemical Name: C₁₄H₁₃NO₂S
• CAS No.: 1360603-77-5
• Molecular Formula: C₁₄H₁₃NO₂S
• Molecular Weight: 259.329
• Mol file: 1360603-77-5.mol

Synonyms:C₁₄H₁₃NO₂S

Chemical Property of C₁₄H₁₃NO₂S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₄H₁₃NO₂S

There total 2 articles about C₁₄H₁₃NO₂S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1-(2-furyl)-1-ethanone (1192-62-7,80145-44-4) + phenyl isothiocyanate (103-72-0) + methyl iodide (74-88-4) → C14H13NO2S (1360603-77-5)

Guidance literature:

1-(2-furyl)-1-ethanone; phenyl isothiocyanate; With sodium hydride; In N,N-dimethyl-formamide; at 20 ℃; for 2h;

methyl iodide; for 1h;

DOI:10.1039/c1gc16129f

Reference yield:

1-Furan-2-yl-3,3-bis-methylsulfanyl-propenone (78078-05-4) + aniline (62-53-3) → C14H13NO2S (1360603-77-5)

Guidance literature:

With boron trifluoride diethyl etherate; In toluene; at 110 ℃; for 2h;

DOI:10.1002/chem.201905483

Reference yield: 87.0%

(E)-1-methoxy-4-(2-nitrovinyl)benzene (3179-10-0,5576-97-6) + C14H13NO2S (1360603-77-5) → 3-(2-furoyl)-4-(4-methoxyphenyl)-2-(methylthio)-1-phenyl pyrrole (1619943-23-5)

Guidance literature:

With indium(III) triflate; at 55 ℃; for 0.0833333h;

DOI:10.1039/c4ob00781f

upstream raw materials:

1-(2-furyl)-1-ethanone

phenyl isothiocyanate

methyl iodide

1-Furan-2-yl-3,3-bis-methylsulfanyl-propenone

Downstream raw materials:

4-(4-chlorophenyl)-3-(2-furoyl)-2-phenylamino-4H-pyrano[3,2-c]chromen-5-one

3-(2-furoyl)-4-phenyl-2-phenylamino-4H-pyrano[3,2-c]chromen-5-one

4-(4-chlorophenyl)-3-(2-furoyl)-7,7-dimethyl-2-phenylamino-4,6,7,8-tetrahydrochromen-5-one

3-(2-furoyl)-4-phenyl-2-phenylamino-4,6,7,8-tetrahydrochromen-5-one

Refernces

• 1、 Singh, Maya Shankar,Nandi, Ganesh Chandra,Samai, Subhasis. "DABCO-Promoted three-component regioselective synthesis of functionalized chromen-5-ones and pyrano[3,2-c]chromen-5-ones via direct annulation of α-oxoketene-N,S-arylaminoacetals under solvent-free conditions". scheme or table. p. 447 - 455. Retrieved 2012/03/26.