dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate

Base Information

• Chemical Name: dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate
• CAS No.: 1260111-93-0
• Molecular Formula: CF₃O₃S*C₁₁H₁₄F₃N₂S
• Molecular Weight: 412.377
• Mol file: 1260111-93-0.mol

Synonyms:dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate

Chemical Property of dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate

There total 1 articles about dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

trifluoromethylsulfonic anhydride (358-23-6) + phenyl trifluoromethyl sulfoxide (703-18-4) + dimethyl amine (124-40-3) + acetonitrile (75-05-8,26809-02-9) → dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate (1260111-93-0)

Guidance literature:

trifluoromethylsulfonic anhydride; phenyl trifluoromethyl sulfoxide; acetonitrile; at -15 ℃; for 24h; Inert atmosphere;

dimethyl amine; In dichloromethane; at -15 - 20 ℃; for 24h; Inert atmosphere;

DOI:10.1002/adsc.201000494

Reference yield: 74.0%

dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate (1260111-93-0) + pent-4-en-1-yl-4-fluorobenzoate → 6,6,6-trifluorohexyl 4-fluorobenzoate

Guidance literature:

With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; rhodamine B; In dichloromethane; at 25 ℃; Irradiation; Inert atmosphere; Flow reactor;

DOI:10.1002/ejoc.201901252

Reference yield: 71.0%

pent-4-en-1-yl 4-chlorobenzoate (99893-78-4) + dimethyl-{1-[(phenyl(trifluoromethyl)-λ4-sulfanylidene)amino]ethylidene}ammonium trifluoromethanesulfonate (1260111-93-0) → 6,6,6-trifluorohexyl-4-chlorobenzoate

Guidance literature:

With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; rhodamine B; In dichloromethane; at 25 ℃; Irradiation; Inert atmosphere; Flow reactor;

DOI:10.1002/ejoc.201901252

upstream raw materials:

trifluoromethylsulfonic anhydride

phenyl trifluoromethyl sulfoxide

dimethyl amine

acetonitrile

Downstream raw materials:

trans-β-(trifluoromethyl)-4-(methoxycarbonyl)-styrene

(E)-1-phenoxy-4-(3,3,3-trifluoroprop-1-en-1-yl)benzene

(E)-1-(3,3,3-trifluoroprop-1-enyl)-4-methoxybenzene

Refernces