Lumirubin

Base Information

• Chemical Name: Lumirubin
• CAS No.: 83664-21-5
• Molecular Formula: C₃₃H₃₆N₄O₆
• Molecular Weight: 584.672
• Mol file: 83664-21-5.mol

Synonyms:Lumirubin IX;

Chemical Property of Lumirubin

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 164.44000
• Density: 1.37g/cm³
• LogP: 4.45600

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Lumirubin

There total 8 articles about Lumirubin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

bilirubin (635-65-4,114-24-9) → Lumirubin (81859-55-4,81859-56-5,83664-21-5,83729-98-0,89616-03-5,89616-04-6,89616-05-7,89617-07-2,92283-86-8,95464-12-3,140629-64-7)

Guidance literature:

With human serum albumin; In water; for 4h; Irradiation; pH 7.4 (phosphate buffer);

DOI:10.1039/c39860000249

Reference yield:

bilirubin (69853-44-7,114-24-9) → bilirubin IXα (635-65-4,69853-42-5,69853-43-6,69853-44-7,148219-49-2,134733-79-2,134733-81-6,114-24-9) + Lumirubin (81859-55-4,81859-56-5,83664-21-5,83729-98-0,89616-03-5,89616-04-6,89616-05-7,89617-07-2,92283-86-8,95464-12-3,140629-64-7)

Guidance literature:

In dichloromethane; Product distribution; Irradiation; solvent effects, various solvents and times;

DOI:10.1139/v87-319

Reference yield:

→ bilirubin (69853-43-6,114-24-9) + lumirubin IX (81859-55-4,81859-56-5,83664-21-5,83729-98-0,89616-03-5,89616-04-6,89616-05-7,89617-07-2,92283-86-8,95464-12-3,140629-64-7) + isolumirubin IX (81859-55-4,81859-56-5,83664-21-5,83729-98-0,89616-03-5,89616-04-6,89616-05-7,89617-07-2,92283-86-8,95464-12-3,140629-64-7)

Guidance literature:

In chloroform; triethylamine; Further byproducts given; Irradiation;

DOI:10.1021/ja00388a104

upstream raw materials:

bilirubin

bilirubin

lumirubin IX

isolumirubin IX

Downstream raw materials:

lumirubin IX

isolumirubin IX

Refernces

• 1、 Kanna, Yoko,Arai, Tatsuo,Tokumaru, Katsumi. "Photoisomerization of Bilirubins and the Role of Intramolecular Hydrogen Bonds". . p. 1482 - 1489. Retrieved 2007/10/02.
• 2、 Kanna, Yoko,Arai, Tatsuo,Sakuragi, Hirochika,Tokumaru, Katsumi. "Effects of Solvents and Media on the Efficiency and Course of Photoisomerization of Bilirubins". . p. 631 - 634. Retrieved 2007/10/02.