monoanilinium 1-phenylethenyl hydrogen phosphate

Base Information

• Chemical Name: monoanilinium 1-phenylethenyl hydrogen phosphate
• CAS No.: 70334-78-0
• Molecular Formula: C₆H₇N*C₈H₉O₄P
• Molecular Weight: 293.259
• Mol file: 70334-78-0.mol

Synonyms:monoanilinium 1-phenylethenyl hydrogen phosphate

Chemical Property of monoanilinium 1-phenylethenyl hydrogen phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of monoanilinium 1-phenylethenyl hydrogen phosphate

There total 3 articles about monoanilinium 1-phenylethenyl hydrogen phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

C17H34ClO4PSi3 + aniline (62-53-3) → monoanilinium 1-phenylethenyl hydrogen phosphate (70334-78-0)

Guidance literature:

With ethanol; In tetrahydrofuran; for 2.5h;

DOI:10.1021/jo00323a024

Reference yield:

1-phenylvinyl dimethyl phosphate (4202-12-4) + aniline (62-53-3) → monoanilinium 1-phenylethenyl hydrogen phosphate (70334-78-0)

Guidance literature:

With trimethylsilyl bromide; Yield given. Multistep reaction; 1) room temperature, 4 h; 2) ethanol;

DOI:10.1021/ja00395a030

Reference yield:

→ monoanilinium 1-phenylethenyl hydrogen phosphate (70334-78-0)

Guidance literature:

Bis(trimethylsilyl)-phosphat 2a, Ethanol/Anilin;

DOI:10.1055/s-1979-28611

upstream raw materials:

1-phenylvinyl dimethyl phosphate

aniline

Downstream raw materials:

disodium 1-phenylvinyl phosphate

monodiisopropylethylammonium 1-phenylethenyl hydrogen phosphate

Refernces

• 1、 Sekine, Mitsuo,Okimoto, Kiyomi,Yamada, Khoji,Hata, Tsujiaki. "Silyl Phosphites. 15. Reactions of Silyl Phosphites with α-Halo Carbonyl Compounds. Elucidation of the Mechanism of the Perkow Reaction and Related Reactions with Confirmed Experiments". . p. 2097 - 2107. Retrieved 2007/10/02.