cesium phenyl(2-phenylcyclopropyl)dimethylborate

Base Information

• Chemical Name: cesium phenyl(2-phenylcyclopropyl)dimethylborate
• CAS No.: 132514-55-7
• Molecular Formula: C₁₇H₂₀B*Cs
• Molecular Weight: 368.062
• Mol file: 132514-55-7.mol

Synonyms:cesium phenyl(2-phenylcyclopropyl)dimethylborate

Chemical Property of cesium phenyl(2-phenylcyclopropyl)dimethylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cesium phenyl(2-phenylcyclopropyl)dimethylborate

There total 1 articles about cesium phenyl(2-phenylcyclopropyl)dimethylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-2-phenylcyclopropane (36617-02-4) + phenylborondichloride (873-51-8) → cesium phenyl(2-phenylcyclopropyl)dimethylborate (132514-55-7)

Guidance literature:

With cesium chloride; methylmagnesium bromide; tert.-butyl lithium; In tetrahydrofuran; diethyl ether; Dropwise addn. of t-C4H9Li to a soln. of 1-bromo-2-phenylcyclopropane in THF at -78°C with stirring. Addn. of CH3MgBr in ether to frozen C6H5BCl2, mixts. are combined, warming to room temp., evapn., dissolved (H2O), addn. of CsCl to aq. soln.; Elem. anal., mixt. of cis:trans (2:3) which cannot be sepd.;

Reference yield: 30.0%

cesium phenyl(2-phenylcyclopropyl)dimethylborate (132514-55-7) → 1-propenylbenzene (873-66-5)

Guidance literature:

With methanol; In tetrahydrofuran; Irradiation (UV/VIS); Further Products.;

Reference yield: 25.0%

cesium phenyl(2-phenylcyclopropyl)dimethylborate (132514-55-7) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + allylbenzene (300-57-2,57807-91-7) + cis-1-phenyl-1-propylene (766-90-5) + 1,3-diphenylpropane (1081-75-0) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

With methanol; In tetrahydrofuran; Irradiation (UV/VIS); Further Products. Purging of a THF soln. of Cs-salt with N2, addn. of MeOH in THF, irradn. at 254 nm.; Monitored by (11)B-NMR and GC.;

upstream raw materials:

1-bromo-2-phenylcyclopropane

phenylborondichloride

Downstream raw materials:

styrene

allylbenzene

cis-1-phenyl-1-propylene

1,3-diphenylpropane

Refernces