cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate

Base Information

• Chemical Name: cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate
• CAS No.: 80529-83-5
• Molecular Formula: C₆₀H₃₆CdN₄
• Molecular Weight: 925.383
• Mol file: 80529-83-5.mol

Synonyms:cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate

Chemical Property of cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate

There total 4 articles about cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

5,10,15,20-tetraphenyl tetrabenzoporphyrin + cadmium(II) acetate (543-90-8) → cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate (80529-83-5)

Guidance literature:

In N,N-dimethyl-formamide; for 0.0166667h; Reflux;

DOI:10.1134/S0036023617050072

Reference yield: 75.0%

cadmium(II) acetate (543-90-8) + meso-tetraphenyltetrabenzoporphyrin (80528-89-8) → cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate (80529-83-5)

Guidance literature:

In N,N-dimethyl-formamide; for 0.0166667h; Reflux;

DOI:10.1134/S1070363216080211

Reference yield: 4.8%

cadmium(II) acetate (543-90-8) + sodium phenylacetate (114-70-5) + potassium phtalimide (1074-82-4) → cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate (80529-83-5)

Guidance literature:

In neat (no solvent); heating (dry N2 current, 350-360°C); grinding, washing (hot water), drying, chromy. (Al2O3, chloroform/petroleum ether 1/1); elem. anal.;

upstream raw materials:

cadmium(II) acetate

sodium phenylacetate

potassium phtalimide

meso-tetraphenyltetrabenzoporphyrin

Downstream raw materials:

copper(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate

zinc(II) tetraphenyltetrabenzoporphinate

platinum(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Refernces

• 1、 Chizhova,Mal’tseva,Zav’yalov,Mamardashvili, N. Zh.. "Copper(II), cobalt(II), cobalt(III), and tin(IV) 5,10,15,20-tetraphenyl tetrabenzoporphyrinates: Synthesis and properties". . p. 683 - 687. Retrieved 2017/06/09.
• 2、 Berezin,Toldina. "Complexation of tetraphenyltetrabenzoporphine with Cu(II), Cd(II), Zn(II), and Co(II) salts in organic solvents". . p. 573 - 578. Retrieved 2008/10/09.