HEXAAMMINECOBALT(III) CHLORIDE

Base Information

• Chemical Name: HEXAAMMINECOBALT(III) CHLORIDE
• CAS No.: 10534-89-1
• Molecular Formula: Cl*CoH₁₈N₆
• Molecular Weight: 196.629
• Hs Code.: 2842908080
• Mol file: 10534-89-1.mol

Synonyms:Cobalt(3+),hexaammine-, trichloride (8CI);Cobalt(3+), hexaammine-, trichloride,(OC-6-11)- (9CI);Hexaaminecobalt trichloride (6CI);Cobalt hexaamminetrichloride;Cobalt hexammine chloride;Cobalt-hexamine chloride;Hexaaminecobalt(3+) trichloride;Hexaamminecobalt chloride;Hexaamminecobalttrichloride;Hexaamminecobalt(3+) trichloride;Hexaamminecobalt(III) chloride;Hexaamminecobalt(III) trichloride;Hexaamminetrichlorocobalt;Hexaminecobalt(3+) trichloride;Hexaminocobaltic chloride;Hexamminecobalt(III)chloride;NSC 4317;

Chemical Property of HEXAAMMINECOBALT(III) CHLORIDE

Chemical Property:

• Appearance/Colour: tan single inclined crystals
• Melting Point: 217 °C(lit.)
• PSA: 19.44000
• Density: 1.71 g/mL at 25 °C(lit.)
• LogP: -7.04460
• Storage Temp.: 2-8°C
• Solubility.: Soluble in ammonia.
• Water Solubility.: Soluble in ammonia and water.

Purity/Quality:

99% ^*data from raw suppliers

Hexaamminecobalt(III) Chloride >99.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: As reagent for pyrophosphoric acid, for the estimation of phosphate. Hexaamminecobalt(III) chloride is a component of structural biology methods, especially for DNA or RNA, where the positive ions stabilize the tertiary structure of the phosphate backbone, which favors to solve their structure by X-ray crystallography. It serves as an excellent antibacterial and antiviral property.

Technology Process of HEXAAMMINECOBALT(III) CHLORIDE

There total 32 articles about HEXAAMMINECOBALT(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.5%

cobalt(II) chloride hexahydrate + salicylaldehyde (90-02-8) → hexammine cobalt(III) chloride (10534-89-1) + tetraammine(salicylideneaminato)cobalt(III) chloride hydrate + diamminebis(salicylideneaminato)cobalt(III) chloride hydrate + diamminebis(salicylideneaminato)cobalt(III) chloride hydrate

Guidance literature:

With ammonia; H₂O₂; In methanol; water; 25% aq. NH3 added to aq. soln. of CoCl2*6H2O, 30% H2O2 added slowly at 0°C, MeOH soln. of salicylaldehyde added dropwise during 2 h at 50°C, stirred for 1 d at 50°C; rotary concd. at 50°C, dried over SiO2, extd. with dry MeOH, concd. as above, ppt. filtered, recrystd. from H2O-EtOH, filtrate chromd. (Al2O3, MeOH), each eluate collected, concd., recrystd. from 10% aq. NH3 or water; elem. anal.;

DOI:10.1246/bcsj.57.2650

Reference yield:

aquapentaamminecobalt(III) perchlorate (13820-81-0) → roseo chloride + hexammine cobalt(III) chloride (10534-89-1) + pentaaminechlorocobalt(III) dichloride (13859-51-3) + (NH3)5Co(C3H2CH3N2H)(3+)*3Cl(1-)

Guidance literature:

With HCl; 4⁽⁵⁾-methylimidazole; In dimethyl sulfoxide; The mixt. of reagents was heated in DMSO at 70°C for 90 min;; exchange on Bio-Rad 200-400 mesh AG 50W-4X resin with aq. HCl, concd. under reduced pressure at 50°C;;

Reference yield:

hexammine cobalt(III) tetranitrodiamminecobaltate → hexammine cobalt(III) chloride (10534-89-1) + nitric acid (7697-37-2,78989-43-2)

Guidance literature:

With hydrogenchloride; In hydrogenchloride; react. of aq. HCl (1:1) with {Co(NH3)6}{Co(NH3)2(NO2)4}3 in the cold; repeated renewal of the HCl; formation of HNO3 and {Co(NH3)6}Cl3;;

upstream raw materials:

hydrogenchloride

ammonia

pentaaminechlorocobalt(III) dichloride

cobalt(II) chloride

Downstream raw materials:

α-triglycinecobalt(III)

α-trialaninecobalt(III)

{Colc3}

[Co(NH₃)6]⁽³⁺⁾*[Co(CO₃)3]^(3-)=[Co(NH₃)6][Co(CO₃)3]

Refernces

• 1、 Yamamoto, Yoshihisa,Toyota, Eiko. "Cobal(III) Complexes with 6-nXn> type Ligands. IV. The Preparation and Properties of Tetraammine(salicylideneaminato)cobalt(III) and Diamminebis(salicylideneaminato)cobalt(III) Complexes". . p. 2650 - 2656. Retrieved 1984.
• 2、 Fan, Dongliang,Feng, Jin,Zhang, Suyun,Lv, Xiaomeng,Gao, Tianyi,Xie, Jimin,Liu, Jun. "Synthesis, structure, and magnetic properties of Ni and Co nanoparticles encapsulated by few-layer h-BN". . p. 153 - 160. Retrieved 2016.
• 3、 Wang, Chenlong,Zhan, Hongju,Lu, Xinhuan,Jing, Run,Zhang, Haifu,Yang, Lu,Li, Xixi,Yue, Fanfan,Zhou, Dan,Xia, Qinghua. "A recyclable cobalt(iii)-ammonia complex catalyst for catalytic epoxidation of olefins with air as the oxidant". . p. 2147 - 2156. Retrieved 2021/02/06.