CYCLOHEPTANONE OXIME

Base Information

• Chemical Name: CYCLOHEPTANONE OXIME
• CAS No.: 2158-31-8
• Molecular Formula: C7H13NO
• Molecular Weight: 127.186
• Hs Code.: 2928000090
• Mol file: 2158-31-8.mol

Synonyms:Suberoxime;Cycloheptanone OxiMe;Cycloheptanon-oxim;Cycloheptanoxim;N-hydroxycycloheptanimine;

Chemical Property of CYCLOHEPTANONE OXIME

Chemical Property:

• Refractive Index: 1.5010-1.5040
• Boiling Point: 231.3°Cat760mmHg
• Flash Point: 127.5°C
• PSA: 32.59000
• Density: 1.07g/cm³
• LogP: 2.17080

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cycloheptanone Oxime ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

Useful:

Technology Process of CYCLOHEPTANONE OXIME

There total 13 articles about CYCLOHEPTANONE OXIME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

cycloheptanone (502-42-1) → cycloheptanone oxime (2158-31-8)

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In methanol; Heating;

DOI:10.1021/jo070297k

Reference yield: 91.0%

1-nitro-1-cycloheptene (36291-53-9) → cycloheptanone oxime (2158-31-8)

Guidance literature:

With zinc(II) tetrahydroborate; In 1,2-dimethoxyethane; at 0 - 5 ℃; for 1.5h;

DOI:10.1016/0040-4039(91)80839-X

Reference yield: 90.0%

cycloheptanol (502-41-0) → cycloheptanone oxime (2158-31-8)

Guidance literature:

cycloheptanol; With chromium(VI) oxide; aluminum oxide; tert-butyl alcohol; for 0.166667h;

With hydroxylamine hydrochloride; for 0.116667h;

DOI:10.1080/10426500490466535

upstream raw materials:

cycloheptanone

2-chlorocycloheptanone oxime

nitrocycloheptane

1-nitro-1-cycloheptene

Downstream raw materials:

1-aza-2-cyclooctanthione

4,5-endo-bis(phenylsulfonyl)-7-oxa-1-azabicyclo<2.2.1>heptane-2-spiro-1'-cycloheptane

cycloheptanone 2,4-dinitrophenylhydrazone

3,3-dichlorohexahydroazocin-2(1H)-one

Refernces

• 1、 Cao, Haoying,Ma, Shanshan,Feng, Yanhong,Guo, Yawen,Jiao, Peng. "Synthesis of β-nitro ketones from geminal bromonitroalkanes and silyl enol ethers by visible light photoredox catalysis". supporting information. p. 1780 - 1783. Retrieved 2022/02/17.
• 2、 Ding, Wei,Mao, Liqiu,Peng, Haoyu,Yin, Dulin,Zhong, Wenzhou. "Site-specific catalytic activities to facilitate solvent-free aerobic oxidation of cyclohexylamine to cyclohexanone oxime over highly efficient Nb-modified SBA-15 catalysts". . p. 3409 - 3422. Retrieved 2020/06/09.