N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester

Base Information

• Chemical Name: N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester
• CAS No.: 1138320-53-2
• Molecular Formula: C₂₀H₃₄N₂S₂
• Molecular Weight: 366.635
• Mol file: 1138320-53-2.mol

Synonyms:N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester

Chemical Property of N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester

There total 3 articles about N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

toluene-4-sulfonic acid 1,1-dibutyl-pentyl ester + carbon disulfide (75-15-0,12122-00-8) + phenylhydrazine (100-63-0) → N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester (1138320-53-2)

Guidance literature:

carbon disulfide; phenylhydrazine; With Amberlite IRA 400; In dimethyl sulfoxide; at 20 ℃; Inert atmosphere;

toluene-4-sulfonic acid 1,1-dibutyl-pentyl ester; In dimethyl sulfoxide; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1080/10426500802203137

Reference yield: 86.0%

carbon disulfide (75-15-0,12122-00-8) + 5-bromo-5-butylnonane (67035-62-5) + phenylhydrazine (100-63-0) → N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester (1138320-53-2)

Guidance literature:

carbon disulfide; phenylhydrazine; With N-benzyl-trimethylammonium hydroxide; In dimethyl sulfoxide; at 20 ℃; Inert atmosphere;

5-bromo-5-butylnonane; In dimethyl sulfoxide; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1007/s00706-008-0873-9

Reference yield: 83.0%

carbon disulfide (75-15-0,12122-00-8) + tri-n-butyl-carbinol (597-93-3) + phenylhydrazine (100-63-0) → N'-phenylhydrazinecarbodithioic acid 1,1-dibutylpentyl ester (1138320-53-2)

Guidance literature:

carbon disulfide; phenylhydrazine; In dimethyl sulfoxide; at 20 ℃; for 0.5h; Inert atmosphere;

tri-n-butyl-carbinol; With triphenylphosphine; diethylazodicarboxylate; In dimethyl sulfoxide; at 20 ℃; for 2h; chemoselective reaction; Inert atmosphere;

DOI:10.1007/BF03249073

upstream raw materials:

carbon disulfide

phenylhydrazine

5-bromo-5-butylnonane

tri-n-butyl-carbinol

Refernces

• 1、 Chaturvedi,Chaturvedi,Mishra,Mishra. "An efficient one-pot synthesis of carbazates and dithiocarbazates through the corresponding alcohols using Mitsunobu's reagent". experimental part. p. 396 - 400. Retrieved 2012/06/18.
• 2、 Chaturvedi, Devdutt,Mishra, Nisha,Chaturvedi, Amit K.,Mishra, Virendra. "Triton-B-catalyzed, efficient, one-pot synthesis of dithiocarbazates through alcoholic tosylates". experimental part. p. 1273 - 1281. Retrieved 2009/10/09.