7αH-8-oxoisolongifolane

Base Information

• Chemical Name: 7αH-8-oxoisolongifolane
• CAS No.: 26839-51-0
• Molecular Formula: C₁₅H₂₄O
• Molecular Weight: 220.355
• Mol file: 26839-51-0.mol

Synonyms:7αH-8-oxoisolongifolane

Chemical Property of 7αH-8-oxoisolongifolane

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7αH-8-oxoisolongifolane

There total 6 articles about 7αH-8-oxoisolongifolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(-)-isolongifolene (1135-66-6) → Isolongifolene β-epoxide (26619-69-2,28370-55-0) + 7αH-8-oxoisolongifolane (26839-51-0) + isolongifolene alcohol

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 3.5h; Yield given. Yields of byproduct given;

DOI:10.1021/jf00037a024

Reference yield:

→ 2,2,7,7-Tetramethyltricyclo<6.2.1.03.8>-undecan-4-on (23787-90-8,26839-48-5,26839-51-0,26839-72-5,29461-13-0,29461-14-1,41746-29-6,41746-30-9,57456-74-3,122743-47-9)

Guidance literature:

Keton IV (<α>(D): +9.2 grad), Filtration ueber akt. Al2O3;

DOI:10.1016/S0040-4020(01)97855-X

Reference yield:

→ (R)-1,1,5,5-Tetramethyl-hexahydro-2,4a-methano-naphthalen-8-one (23787-90-8,26839-48-5,26839-51-0,26839-72-5,29461-13-0,29461-14-1,41746-29-6,41746-30-9,57456-74-3,122743-47-9)

Guidance literature:

Verb. 1, BF3-katalys. Umlagerung;

DOI:10.1016/S0040-4039(01)98518-1

upstream raw materials:

(-)-isolongifolene

Downstream raw materials:

(-)-isolongifolene

7βH-8-Oxoisolongifolane tosylhydrazone

Refernces