3-METHYLDIPHENYLSULFIDE

Base Information

• Chemical Name: 3-METHYLDIPHENYLSULFIDE
• CAS No.: 13865-48-0
• Molecular Formula: C13H12 S
• Molecular Weight: 200.304
• Hs Code.: 2930909090
• Mol file: 13865-48-0.mol

Synonyms:Sulfide,phenyl m-tolyl (6CI,7CI,8CI); 3-Methylphenyl phenyl sulfide; Phenyl 3-tolylsulfide; Phenyl m-tolyl sulfide; Phenyl m-tolyl sulfide; m-(Phenylthio)toluene

Chemical Property of 3-METHYLDIPHENYLSULFIDE

Chemical Property:

• Vapor Pressure: 0.00112mmHg at 25°C
• Melting Point: -6.5°C
• Refractive Index: 1.6170 (estimate)
• Boiling Point: 310.1°Cat760mmHg
• Flash Point: 135.9°C
• PSA: 25.30000
• Density: 1.1g/cm³
• LogP: 4.14620

Purity/Quality:

99%min ^*data from raw suppliers

3-METHYL DLPHENYL SULFIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-METHYLDIPHENYLSULFIDE

There total 55 articles about 3-METHYLDIPHENYLSULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-chloro-3-methylbenzene (108-41-8) + thiophenol (108-98-5) → 3-methylphenyl phenyl sulfide (13865-48-0)

Guidance literature:

With tetrakis(tri-p-tolylphosphite)nickel⁽⁰⁾; potassium tert-butylate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; zinc; In toluene; at 110 ℃; for 16h; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.orglett.7b03560

Reference yield: 99.0%

3-Iodotoluene (625-95-6) + thiophenol (108-98-5) → 3-methylphenyl phenyl sulfide (13865-48-0)

Guidance literature:

With 1,10-Phenanthroline; caesium carbonate; manganese(ll) chloride; In toluene; at 135 ℃; for 48h; Inert atmosphere;

DOI:10.1002/asia.201300045

Reference yield: 99.0%

iodobenzene (591-50-4) + toluene-3-thiol (108-40-7) → 3-methylphenyl phenyl sulfide (13865-48-0)

Guidance literature:

With copper(l) iodide; potassium phosphate tribasic trihydrate; In water; at 110 ℃; for 12h;

DOI:10.1016/j.tetlet.2008.11.082

upstream raw materials:

meta-bromotoluene

copper(I) thiophenolate

aniline

thiophenol

Downstream raw materials:

3-methyldiphenylsulphone

1-methyl-3-(phenylsulfinyl)benzene

3-methyl-dibenzothiophene

1-methyldibenzo[b,d]thiophene

Refernces

• 1、 Bunnett,J.F.,Creary,X.. "-". . p. 3173 - 3174. Retrieved 1974.
• 2、 Huang, Wei-Kai,Chen, Wei-Ting,Hsu, I.-Jui,Han, Chien-Chung,Shyu, Shin-Guang. "Cross C-S coupling reaction catalyzed by copper(i) N-heterocyclic carbene complexes". . p. 4912 - 4920. Retrieved 2017.
• 3、 Cargnelutti, Roberta,Lang, Ernesto S.,Schumacher, Ricardo F.. "Bis(2-pyridyl)diselenoethers as versatile ligands for copper-catalyzed C-S bond formation in glycerol". . p. 5218 - 5222. Retrieved 2015.
• 4、 Shen, Guodong,Lu, Qichao,Wang, Zeyou,Sun, Weiwei,Zhang, Yalin,Huang, Xianqiang,Sun, Manman,Wang, Zhiming. "Environmentally Friendly and Recyclable CuCl 2-Mediated C-S Bond Coupling Strategy Using DMEDA as Ligand, Base, and Solvent". supporting information. p. 184 - 198. Retrieved 2021/09/20.
• 5、 Morandi, Bill,Rivero-Crespo, Miguel A.,Toupalas, Georgios. "Preparation of Recyclable and Versatile Porous Poly(aryl thioether)s by Reversible Pd-Catalyzed C–S/C–S Metathesis". supporting information. p. 21331 - 21339. Retrieved 2021/12/17.