benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate

Base Information

• Chemical Name: benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate
• CAS No.: 1610968-09-6
• Molecular Formula: C₂₅H₄₁NO₂
• Molecular Weight: 387.606
• Mol file: 1610968-09-6.mol

Synonyms:benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate

Chemical Property of benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate

There total 4 articles about benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(9Z)-N-hydroxy-octadecenecarboxamide + benzyl chloroformate (501-53-1,94274-21-2) → benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate (1610968-09-6)

Guidance literature:

(9Z)-N-hydroxy-octadecenecarboxamide; With potassium carbonate; In dimethyl sulfoxide; at 90 ℃; for 7h;

benzyl chloroformate; With sodium hydroxide; In water; dimethyl sulfoxide; for 12h;

DOI:10.1039/c6ob01178k

Reference yield: 75.0%

Oleylhydroxamic acid (10335-69-0) + benzyl alcohol (100-51-6,185532-71-2) → benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate (1610968-09-6)

Guidance literature:

With DBC; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; at 120 ℃; Green chemistry;

DOI:10.1039/c4gc00273c

Reference yield:

cis-10-nonadecenoic acid methyl ester (19788-74-0) → benzyl N-[(8Z)-heptadec-8-en-1-yl]carbamate (1610968-09-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: hydroxylamine hydrochloride; potassium hydroxide / methanol / 12 h / 20 °C / pH 10

2.1: potassium carbonate / dimethyl sulfoxide / 7 h / 90 °C

2.2: 12 h

With hydroxylamine hydrochloride; potassium carbonate; potassium hydroxide; In methanol; dimethyl sulfoxide; 2.1: |Lossen Rearrangement;

DOI:10.1039/c6ob01178k

upstream raw materials:

Oleylhydroxamic acid

benzyl alcohol

Methyl oleate

benzyl chloroformate

Refernces

• 1、 Winkler, Matthias,Meier, Michael A. R.. "Olefin cross-metathesis as a valuable tool for the preparation of renewable polyesters and polyamides from unsaturated fatty acid esters and carbamates". supporting information. p. 3335 - 3340. Retrieved 2014/06/10.