C₁₈H₃₂OP₂S

Base Information

• Chemical Name: C₁₈H₃₂OP₂S
• CAS No.: 1602920-41-1
• Molecular Formula: C₁₈H₃₂OP₂S
• Molecular Weight: 358.465
• Mol file: 1602920-41-1.mol

Synonyms:C₁₈H₃₂OP₂S

Chemical Property of C₁₈H₃₂OP₂S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₈H₃₂OP₂S

There total 2 articles about C₁₈H₃₂OP₂S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

Chlorodiisopropylphosphane (40244-90-4) + 3-mercaptophenol (40248-84-8) → C18H32OP2S (1602920-41-1)

Guidance literature:

3-mercaptophenol; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 1h; Schlenk technique; Glovebox;

Chlorodiisopropylphosphane; In tetrahydrofuran; at 20 ℃; for 1h; Schlenk technique; Glovebox;

DOI:10.1002/anie.201306559

Reference yield:

Chlorodiisopropylphosphane (40244-90-4) + 3,3’-dihydroxydiphenyl disulfide (21101-56-4) → C18H32OP2S (1602920-41-1)

Guidance literature:

3,3’-dihydroxydiphenyl disulfide; With triethylamine; In toluene; at 20 ℃; for 0.166667h; Inert atmosphere; Schlenk technique;

Chlorodiisopropylphosphane; In toluene; for 12h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1016/j.ica.2019.119283

upstream raw materials:

Chlorodiisopropylphosphane

3-mercaptophenol

3,3’-dihydroxydiphenyl disulfide

Refernces

• 1、 Valderrama-García, Bianca X.,Rufino-Felipe, Ernesto,Valdés, Hugo,Hernandez-Ortega, Simón,Aguilar-Castillo, Bethsy Adriana,Morales-Morales, David. "Novel and facile procedure for the synthesis of Ni(II) and Pd(II) PSCOP pincer complexes. Evaluation of their catalytic activity on C-S, C-Se and C-C cross coupling reactions". . . Retrieved 2019/12/09.