Technology Process of (6aS,12aS,5'S)-5'-phenylsulfinyl-4',5'-dihydrodeguelin
There total 4 articles about (6aS,12aS,5'S)-5'-phenylsulfinyl-4',5'-dihydrodeguelin which
guide to synthetic route it.
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synthetic route:
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145484-41-9
(2S,7aS,13aS)-2-Benzenesulfonyl-9,10-dimethoxy-3,3-dimethyl-2,3,13,13a-tetrahydro-1H,7aH-pyrano[2,3-c;6,5-f']dichromen-7-one
- Guidance literature:
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With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
for 20h;
Ambient temperature;
darkness;
- Guidance literature:
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Multi-step reaction with 4 steps
1: N-chlorosuccinimide / CH2Cl2 / Heating
2: CH2Cl2 / 2 h / -35 - 20 °C
3: sodium cyanoborohydride / hexamethylphosphoric acid triamide / 2 h / Ambient temperature
4: 60 percent / m-chloroperbenzoic acid / CH2Cl2 / 20 h / Ambient temperature; darkness
With
N-chloro-succinimide; sodium cyanoborohydride; 3-chloro-benzenecarboperoxoic acid;
In
N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;
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124571-92-2
(1S,2R,7aS,13aS)-1-Chloro-9,10-dimethoxy-3,3-dimethyl-2-phenylsulfanyl-2,3,13,13a-tetrahydro-1H,7aH-pyrano[2,3-c;6,5-f']dichromen-7-one
- Guidance literature:
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Multi-step reaction with 2 steps
1: sodium cyanoborohydride / hexamethylphosphoric acid triamide / 2 h / Ambient temperature
2: 60 percent / m-chloroperbenzoic acid / CH2Cl2 / 20 h / Ambient temperature; darkness
With
sodium cyanoborohydride; 3-chloro-benzenecarboperoxoic acid;
In
N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane;