Tetraphenylarsonium chloride

Base Information

• Chemical Name: Tetraphenylarsonium chloride
• CAS No.: 507-28-8
• Molecular Formula: C₂₄H₂₀As*Cl
• Molecular Weight: 418.797
• European Community (EC) Number: 208-070-6
• NSC Number: 18857
• UNII: AG51MKF20J
• DSSTox Substance ID: DTXSID20964938
• Wikipedia: Tetraphenylarsonium_chloride
• Wikidata: Q3680971
• Mol file: 507-28-8.mol

Synonyms:tetraphenylarsonium;tetraphenylarsonium bromide;tetraphenylarsonium chloride;tetraphenylarsonium thiocyanate

Chemical Property of Tetraphenylarsonium chloride

Chemical Property:

• Appearance/Colour: crystalline solid
• Melting Point: 258-260 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.06800
• Water Solubility.: Freely soluble in water. Soluble in alcohol. Sparingly soluble in acetone
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 418.046948
• Heavy Atom Count: 26
• Complexity: 301

Purity/Quality:

98% ^*data from raw suppliers

Tetraphenylarsonium chloride monohydrate, 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R23/25:Toxic by inhalation and if swallowed.; R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects
• Hazard Codes: T,N
• Statements: 23/25-50/53
• Safety Statements: 20/21-28-45-60-61

MSDS Files:

Useful:

• Chemical Classes: Metals -> Arsenic Compounds, Organic
• Canonical SMILES: C1=CC=C(C=C1)[As+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Cl-]
• Uses: Cation exchange reagent. Used to prepare arsonium amide, oxime, and carbohydrate derivatives.

Technology Process of Tetraphenylarsonium chloride

There total 8 articles about Tetraphenylarsonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Ph4As[Ir(CO)2Cl2] (15152-88-2,29629-78-5) + (diphenylphosphinomethyl)diphenylphosphine selenide (23176-19-4) → Ir(CO)Cl(PPh2CH2P(Se)Ph2)2 + tetraphenylarsonium chloride (507-28-8,14842-08-1)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.005h;

DOI:10.1016/j.poly.2020.114344

Reference yield:

triphenylarsineoxide (1153-05-5,856568-31-5) + phenylmagnesium bromide → tetraphenylarsonium chloride (507-28-8,14842-08-1)

Guidance literature:

With diethyl ether; benzene; anschliessend mit wss.Salzsaeure;

DOI:10.1021/ja01870a028

Reference yield:

Tetraphenylarsonium chloride (60805-89-2) → tetraphenylarsonium chloride (507-28-8,14842-08-1)

Guidance literature:

With hydrogenchloride; at -78 ℃; Yield given;

upstream raw materials:

triethyl arsenate

triphenylarsineoxide

triphenyl-arsane

chlorobenzene

Downstream raw materials:

bis(tetraphenylarsonium) 1,2-bis(N-perfluoro-n-propyl-N-sulphonatoamino-oxyl)-1-chloro-1,2,2-trifluoroethane

tetraphenylarsonium tetraphenylborate

Refernces

• 1、 Mueller, Ulrich,Doerner, Hans-Dieter. "A New Synthesis, the Vibrational Spectrum and the Crystal Structure of Tetraphenylarsonium Hydrogendichloride As(C6H5)4". . p. 198 - 200. Retrieved 2007/10/02.