Sodium 4-nitrophenoxide

Base Information

• Chemical Name: Sodium 4-nitrophenoxide
• CAS No.: 824-78-2
• Molecular Formula: C6H4NNaO3
• Molecular Weight: 161.092
• Hs Code.: 29089910
• Mol file: 824-78-2.mol

Synonyms:Phenol,4-nitro-, sodium salt (9CI);Phenol, p-nitro-, sodium deriv. (6CI);Phenol,p-nitro-, sodium salt (8CI);Sodium, (p-nitrophenoxy)- (7CI);4-Nitrophenolsodium salt;Sodium 4-nitrophenolate;Sodiump-nitrophenol;Sodium p-nitrophenolate;Sodium p-nitrophenoxide;p-Nitrophenolsodium salt;Sodium 4-nitrophenoxide;

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Chemical Property of Sodium 4-nitrophenoxide

Chemical Property:

• Appearance/Colour: yellow to orange-yellow needle crystals
• Vapor Pressure: 0.00243mmHg at 25°C
• Melting Point: >300 °C(lit.)
• Boiling Point: 279 °C at 760 mmHg
• Flash Point: 141.9 °C
• PSA: 68.88000
• LogP: 2.26180

Purity/Quality:

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-33
• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

Useful:

Technology Process of Sodium 4-nitrophenoxide

There total 120 articles about Sodium 4-nitrophenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrophenyl decanoate (1956-09-8) → sodium decanoate (1002-62-6) + 4-nitrophenol sodium salt (824-78-2)

Guidance literature:

With buffer (0.05 M H₂PO₄^-/HPO₄^2-); sodium chloride; In 1,4-dioxane; methanol; at 30 ℃; Rate constant; pH 8; other p-nitrophenyl alkanoates, var. conc. of p-pyrimidyl comp. and NaCl;

DOI:10.1021/ja961505l

Reference yield:

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + sodium anisate (536-45-8) → 4-methoxybenzoic acid (100-09-4) + 4-nitrophenol sodium salt (824-78-2)

Guidance literature:

With 1-butyl-2,3-dimethylimidazolium bis-(trifluoromethanesulfonyl)amide; In methanol; at 24.84 ℃; Reagent/catalyst; Equilibrium constant;

DOI:10.1021/jo100914p

Reference yield:

p-nitrophenyl hexanoate (956-75-2) → sodium caproate (10051-44-2) + 4-nitrophenol sodium salt (824-78-2)

Guidance literature:

With sodium hydroxide; macroporous poly(styrene-divinylbenzene); In water; acetonitrile; at 23 ℃; Rate constant; var. composition of equilibration solvent;

DOI:10.1021/jo00252a020

upstream raw materials:

para-dinitrobenzene

2-(4-nitrophenoxy)tetrahydropyran

p-nitrophenyl methyl sulfoxide

bis-(p-nitrophenyl) carbonate

Downstream raw materials:

p‐nitrophenyl 2‐bromopropionate

(4-nitro-phenoxy)-malonic acid diethyl ester

1-(ethylsulfanyl)-4-nitrobenzene

1-ethoxy-4-nitrobenzene

Refernces

• 1、 Zhang, Yingfang,Xia, Yan,Yan, Saisai,Han, Jia,Chen, Yifan,Zhai, Wenzhong,Gao, Zhinong. "One-step green synthesis of composition-tunable Pt-Cu alloy nanowire networks with high catalytic activity for 4-nitrophenol reduction". . p. 17461 - 17468. Retrieved 2018.
• 2、 Tabe, Hiroyasu,Matsushima, Masaaki,Tanaka, Rika,Yamada, Yusuke. "Creation and stabilisation of tuneable open metal sites in thiocyanato-bridged heterometallic coordination polymers to be used as heterogeneous catalysts". . p. 17063 - 17069. Retrieved 2019.
• 3、 Zakharova,Ibragimova,Valeeva,Zakharov,Kudryavtseva,Konovalov,Zakharchenko,Zuev. "Influence of temperature on the reactivity of phosphorus acid esters in reverse micellar systems based on sodium bis(2-ethylhexyl)sulfosuccinate". . p. 1449 - 1457. Retrieved 2005.
• 4、 Bel'skii, V. E.,Valeeva, F. G.,Kudryavtseva, L. A.,Ivanov, B. E.. "SOLVENT EFFECT ON THE RATE OF ESTER INTERCHANGE OF p-NITROPHENYLDIETHYLPHOSPHATE". . p. 1738 - 1741. Retrieved 1991.
• 5、 Moss, Robert A.,Bose, Susmita. "Kinetics of the micellar nucleophilic cleavage of diastereomeric phosphotriesters". . p. 965 - 968. Retrieved 1997.
• 6、 Yadav, Vishal,Siegler, Maxime A.,Goldberg, David P.. "Temperature-Dependent Reactivity of a Non-heme FeIII(OH)(SR) Complex: Relevance to Isopenicillin N Synthase". supporting information. p. 46 - 52. Retrieved 2021/01/13.
• 7、 -. "Preparation method of sodium p-nitrophenolate". Paragraph 0020-0026. . Retrieved 2020/04/22.