benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone

Base Information

• Chemical Name: benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone
• CAS No.: 75142-62-0
• Molecular Formula: C₂₂H₃₀N₂O₂S
• Molecular Weight: 386.558
• Mol file: 75142-62-0.mol

Synonyms:benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone

Chemical Property of benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone

There total 1 articles about benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

trisylhydrazine (39085-59-1) + benzaldehyde (100-52-7) → benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone (75142-62-0)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 3h;

DOI:10.1021/jacs.6b11336

Reference yield: 98.0%

tributyl borane (122-56-5) + benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone (75142-62-0) → pentylbenzene (538-68-1)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In tetrahydrofuran; methanol; for 1h; Heating;

DOI:10.1021/jo962089q

Reference yield: 95.0%

benzaldehyde 2,4,6-tri-isopropylbenzenesulphonyl hydrazone (75142-62-0) → phenyldiazomethane (908094-04-2)

Guidance literature:

With potassium hydroxide; In methanol; for 0.116667h; Heating;

DOI:10.1016/j.tetlet.2006.06.065

upstream raw materials:

trisylhydrazine

benzaldehyde

Downstream raw materials:

benzyl methyl ether

Benzyl isocyanide

phenylacetonitrile

phenyldiazomethane

Refernces

• 1、 Deb, Arghya,Ke, Jing,Wang, Xiaoxu,Xu, Yijie,Zhang, X. Peter,Zhu, Yiling. "Asymmetric Radical Process for General Synthesis of Chiral Heteroaryl Cyclopropanes". supporting information. p. 11121 - 11129. Retrieved 2021/08/03.
• 2、 -. "PROCESS FOR THE CYCLOADDITION OF A HETERO(ARYL) 1,3-DIPOLE COMPOUND WITH A (HETERO)CYCLOALKYNE". Paragraph 0413. . Retrieved 2017/01/26.