Oxamyl oxime

Base Information

• Chemical Name: Oxamyl oxime
• CAS No.: 30558-43-1
• Molecular Formula: C5H10N2O2S
• Molecular Weight: 162.213
• Hs Code.: 2930909090
• European Community (EC) Number: 250-239-1
• UN Number: 3082
• UNII: 7DQA20DYUR
• DSSTox Substance ID: DTXSID601338880
• Nikkaji Number: J124.907J
• Wikidata: Q27291456
• Mol file: 30558-43-1.mol

Synonyms:Oxamyl oxime;Oxamyl oxime, (E)-;UNII-7DQA20DYUR;7DQA20DYUR;30558-43-1;66344-32-9;Methyl 2-(dimethylamino)-N-hydroxy-2-oxothioimidoacetate;Oxamyl-oxime 10 microg/mL in Acetonitrile;Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-oxo-, methyl ester, (E)-;A2213;(E)-oxamyl oxime;EINECS 250-239-1;BRN 1929813;RCRA waste no. U394;A-2213;2-(Dimethylamino)-N-hydroxy-2-oxoethanimidothioic acid methyl ester;SCHEMBL10966565;DTXSID601338880;AKOS006278984;LS-66226;A 2213;J-018010;Q27291456;2-(Hydroxyimino)-N,N-dimethyl-2-(methylthio)acetamide;methyl (1E)-2-(dimethylamino)-N-hydroxy-2-oxoethanimidothioate

Chemical Property of Oxamyl oxime

Chemical Property:

• Vapor Pressure: 0.000805mmHg at 25°C
• Refractive Index: 1.6430 (estimate)
• Boiling Point: 272.1°Cat760mmHg
• PKA: 9.39±0.10(Predicted)
• Flash Point: 118.3°C
• PSA: 78.20000
• Density: 1.2g/cm³
• LogP: 0.22530
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 162.04629874
• Heavy Atom Count: 10
• Complexity: 156

Purity/Quality:

99%, ^*data from raw suppliers

OximinoOxamyl ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Oximes
• Canonical SMILES: CN(C)C(=O)C(=NO)SC
• Isomeric SMILES: CN(C)C(=O)/C(=N\O)/SC
• Uses: Oximino Oxamyl can be used as a metabolite of Oxamyl in fruits of apple, orange, and tomato. Oxamyl is used as insecticide and acaricide in plants.

Technology Process of Oxamyl oxime

There total 2 articles about Oxamyl oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oxamyl (23135-22-0) → carbon dioxide (124-38-9,18923-20-1) + methyl 2-(dimethylamino)-N-hydroxy-2-oxoethanimidothioate (30558-43-1) + methylamine (74-89-5)

Guidance literature:

With borate buffer; cetyltrimethylammonim bromide; In water; at 100 ℃; for 0.00833333h; pH=9.0; Further Variations:; Temperatures; Product distribution;

DOI:10.1021/ac990928d

Reference yield:

→ methyl 2-(dimethylamino)-N-hydroxy-2-oxoethanimidothioate (30558-43-1)

Guidance literature:

Reference yield:

methyl 2-(dimethylamino)-N-hydroxy-2-oxoethanimidothioate (30558-43-1) + methyl isocyanate (624-83-9) → oxamyl (23135-22-0)

Guidance literature:

With triethylamine; In water; at 42 ℃; Inert atmosphere;

upstream raw materials:

oxamyl

Downstream raw materials:

oxamyl

Refernces