4-nitro-N-nitrosoaniline

Base Information

• Chemical Name: 4-nitro-N-nitrosoaniline
• CAS No.: 32352-96-8
• Molecular Formula: C6H5N3O3
• Molecular Weight: 189.106
• Mol file: 32352-96-8.mol

Synonyms:

Chemical Property of 4-nitro-N-nitrosoaniline

Chemical Property:

• Vapor Pressure: 0.00209mmHg at 25°C
• Boiling Point: 290.3°Cat760mmHg
• Flash Point: 129.4°C
• Density: 1.48g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-nitro-N-nitrosoaniline

There total 2 articles about 4-nitro-N-nitrosoaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrobenzenediazonium tetrafluoroborate (456-27-9) → 4-nitro-benzenediazohydroxide, sodium salt (32352-96-8)

Guidance literature:

With sodium hydroxide; In water; at 0 - 55 ℃; for 0.833333h;

DOI:10.1002/anie.202014842

Reference yield:

4-nitrobenzenediazonium tetrafluoroborate (456-27-9) → (E)-4-nitro-benzenediazo hydroxide; sodium-salt (32352-96-8)

Guidance literature:

With sodium hydroxide; at 20 ℃;

Reference yield: 83.0%

chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) + (E)-4-nitro-benzenediazo hydroxide; sodium-salt (32352-96-8) → η-cyclopentadienyl(anti-p-nitrobenzenediazoato-N1)(triphenylphosphine)nickel(II) (83691-47-8)

Guidance literature:

In tetrahydrofuran; ligand added portionwise to stirred soln. of Ni-complex in THF under N2, allowed to stand for 30 min at room temp.; filtered through Celite, evapd, in vac., washed with Et2O, dissolved inCH2Cl2, filtered through Celite, hexane added, concd. without heat in vac.; elem. anal.;

upstream raw materials:

4-nitrobenzenediazonium tetrafluoroborate

Downstream raw materials:

2-(4-nitro-phenylhydrazono)-3-oxo-glutaric acid diethyl ester

3-(4-nitro-phenylazomethylene)-4-phenyl-3,4-dihydro-benzo[f]quinoline

3-(4-nitro-phenylazomethylene)-4-p-tolyl-3,4-dihydro-benzo[f]quinoline

2-(4-nitro-phenylazomethylene)-1-phenyl-1,2-dihydro-quinoline

Refernces

• 1、 Bagal,Luchkevich,El'tsov. "Transformations of Diazonium Salts. III. Transformations, Acid-Base Properties, and Reactivity of Nitronaphthyldiazonium Salts". . p. 119 - 132. Retrieved 2007/10/03.