Tris(2,4-di-tert-butylphenyl)phosphate

Base Information

• Chemical Name: Tris(2,4-di-tert-butylphenyl)phosphate
• CAS No.: 95906-11-9
• Molecular Formula: C42H63O4P
• Molecular Weight: 662.934
• Mol file: 95906-11-9.mol

Synonyms:

Chemical Property of Tris(2,4-di-tert-butylphenyl)phosphate

Chemical Property:

• Boiling Point: 609.8±55.0 °C(Predicted)
• PSA: 54.57000
• Density: 1.007±0.06 g/cm3(Predicted)
• LogP: 13.11650

Purity/Quality:

99% ^*data from raw suppliers

Tris(2,4-di-tert-butylphenyl)phosphate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Tris(2,4-di-tert-butylphenyl)phosphate is used as a processing stabilizer for polymers.

Technology Process of Tris(2,4-di-tert-butylphenyl)phosphate

There total 5 articles about Tris(2,4-di-tert-butylphenyl)phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

tris(2,4-di-tert-butylphenyl)phosphite (31570-04-4) → tris(2,4-di(tert-butyl)phenyl) phosphate (95906-11-9)

Guidance literature:

With iodine; In tetrahydrofuran; water; at 20 ℃; for 1h;

DOI:10.1021/op000026a

Reference yield:

Cumene hydroperoxide (80-15-9) + tris(2,4-di-tert-butylphenyl)phosphite (31570-04-4) → 1-methyl-1-phenylethyl alcohol (617-94-7) + tris(2,4-di(tert-butyl)phenyl) phosphate (95906-11-9)

Guidance literature:

In chlorobenzene; at 29.9 ℃; Rate constant; Mechanism;

Reference yield:

2,4-di-tert-Butylphenol (96-76-4) → tris(2,4-di(tert-butyl)phenyl) phosphate (95906-11-9)

Guidance literature:

With phosphorous; iron(III) 2,2,6,6-tetramethyl-3,5-heptanedioneate; iodine; oxygen; In toluene; at 80 ℃;

DOI:10.1002/ejic.201100046

upstream raw materials:

Cumene hydroperoxide

tris(2,4-di-tert-butylphenyl)phosphite

2,4-di-tert-Butylphenol

Refernces

• 1、 Armstrong, Kenneth M.,Kilian, Petr. "Catalytic synthesis of triaryl phosphates from white phosphorus". experimental part. p. 2138 - 2147. Retrieved 2011/06/28.
• 2、 Koenig, T.,Habicher, W. D.,Schwetlick, K.. "Organophosphorus Antioxidants. X. The Hydroperoxide Decomposing Action of Phosphites, Phosphonites and Thiophosphites". . p. 913 - 922. Retrieved 2007/10/02.