1,1-Dimethylhydrazine hydrochloride

Base Information

• Chemical Name: 1,1-Dimethylhydrazine hydrochloride
• CAS No.: 593-82-8
• Molecular Formula: C2H8 N2 . Cl H
• Molecular Weight: 96.5599
• Hs Code.: 2928000090
• European Community (EC) Number: 209-811-6
• DSSTox Substance ID: DTXSID30208037
• Mol file: 593-82-8.mol

Synonyms:1,1-DIMETHYLHYDRAZINE HYDROCHLORIDE;593-82-8;1,1-Dimethylhydrazine HCl;1,1-Dimethylhydrazine monohydrochloride;Hydrazine, 1,1-dimethyl-, hydrochloride;1,1-dimethylhydrazine;hydrochloride;EINECS 209-811-6;Hydrazine, 1,1-dimethyl-, monohydrochloride;N,N-Dimethylhydrazine (hydrochloride);1,1-DiMethylhydrazine (hydrochloride);dimazine hydrochloride;C2H8N2.ClH;1,1-DimethylhydrazineHCl;C2H8N2.HCl;dimethylhydrazine hydrochloride;1,1-Dimethyl-d6-hydrazine hcl;CHROMANE-2-CARBOXYLICACID;DTXSID30208037;CS-M2143;MFCD00060207;AKOS027328059;GS-5467;LS-76759;1,1-Dimethylhydrazine hydrochloride (asym);D0742;FT-0667459;FT-0695268;H10568

Chemical Property of 1,1-Dimethylhydrazine hydrochloride

Chemical Property:

• Vapor Pressure: 168mmHg at 25°C
• Melting Point: 85°C
• Boiling Point: 63.9°Cat760mmHg
• Flash Point: 1.1°C
• PSA: 29.26000
• Density: 0.829g/cm³
• LogP: 0.92400
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: almost transparency
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 96.0454260
• Heavy Atom Count: 5
• Complexity: 11.5

Purity/Quality:

99% ^*data from raw suppliers

1,1-Dimethylhydrazine Hydrochloride ^*data from reagent suppliers

Safty Information:

• Statements: 20/21-28
• Safety Statements: 22-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)N.Cl
• Uses: 1,1-Dimethylhydrazine Hydrochloride is a toxic volatile hydrazine found in rocket fuel systems.

Technology Process of 1,1-Dimethylhydrazine hydrochloride

There total 6 articles about 1,1-Dimethylhydrazine hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1,2-dichlorovinyl propyl ketone (882037-58-3) + N,N-Dimethylhydrazine (57-14-7) → N,N-dimethylhydrazine hydrochloride (593-82-8,55484-54-3)

Guidance literature:

In diethyl ether;

DOI:10.1007/s11178-005-0064-7

Reference yield: 63.2%

N,N-dimethylammonium chloride (506-59-2) → N,N-dimethylhydrazine hydrochloride (593-82-8,55484-54-3)

Guidance literature:

N,N-dimethylammonium chloride; With sodium nitrite; In water; at 20 ℃; Cooling with ice;

With zinc; In water; at 20 ℃; Cooling with ice;

Reference yield: 54.0%

1-(2-carbamylethyl)-1,1-dimethylhydrazinium chloride (6439-49-2) → N,N-dimethylhydrazine hydrochloride (593-82-8,55484-54-3) + 3-hydroxypropanoic acid sodium salt (6487-38-3)

Guidance literature:

With sodium hydroxide; for 1.5h; Heating;

upstream raw materials:

N-Nitrosodimethylamine

1-(2-carbamylethyl)-1,1-dimethylhydrazinium chloride

1,2-dichlorovinyl propyl ketone

N,N-Dimethylhydrazine

Downstream raw materials:

2,2-Dimethyl-3-phenyl-1,2,3,3a,4,11c-hexahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

1,1-dimethyl-3,5-diphenylpyrazolidinium chloride

1,1-dimethyl-4-(methoxycarbonyl)-3-phenylpyrazolidinium chloride

2-(Dimethyl-hydrazono)-1-p-tolyl-ethanone

Refernces

• 1、 Bozhenkov,Leckovskaya,Larina,Ushakov,Dolgushin,Mirskova. "Synthesis, structure, and characteristics of 1,2-dichlorovinyl alkyl ketones". . p. 1583 - 1592. Retrieved 2007/10/03.