Dichloroglyoxime

Base Information

• Chemical Name: Dichloroglyoxime
• CAS No.: 2038-44-0
• Molecular Formula: C2H2Cl2N2O2
• Molecular Weight: 156.956
• Hs Code.: 2925290090
• Mol file: 2038-44-0.mol

Synonyms:Ethanediimidoyldichloride, dihydroxy- (9CI);Glyoxime, dichloro- (6CI,7CI);Oxalohydroximoylchloride (8CI);1,2-Dichloroglyoxime;Ethanedioyldichloride, dioxime;NSC 528431;Oxalyl chloride, dioxime;

Chemical Property of Dichloroglyoxime

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 213°C (dec.)
• Refractive Index: 1.575
• Boiling Point: 334.6 °C at 760 mmHg
• PKA: 3.45±0.10(Predicted)
• Flash Point: 156.1 °C
• PSA: 65.18000
• Density: 1.8 g/cm³
• LogP: 1.03940

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dichloroglyoxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dichloroglyoxime

There total 10 articles about Dichloroglyoxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

diaminoglyoxime (2580-79-2) → dichloroglyoxime (2038-44-0)

Guidance literature:

With hydrogenchloride; sodium nitrite; In water; at 20 ℃; for 22h; Cooling with ice;

Reference yield: 94.0%

glyoxime (557-30-2) → dichloroglyoxime (2038-44-0)

Guidance literature:

With N-chloro-succinimide; In N,N-dimethyl-formamide; at 0 - 50 ℃; for 3h;

DOI:10.1002/cjoc.201600599

Reference yield: 26.0%

3-amino-3-hydroximinopropane hydroxamic acid (56366-92-8) → dichloroglyoxime (2038-44-0)

Guidance literature:

With hydrogenchloride; sodium nitrite; at 0 - 5 ℃; for 1h;

DOI:10.1080/00397919208055423

upstream raw materials:

glyoxime

(E,E)-monochloroglyoxime

(1Z,2E)-N-hydroxy-2-(hydroxyimino)-acetimidoyl chloride

3-Brom-3,3-dinitro-propionitril

Downstream raw materials:

dianilineglyoxime

ruthenium(II)(dichloroglyoxime)3(BC₆H₅)2

dimesitylglyoxal dioxime

Refernces

• 1、 Tao, Jingjing,Jin, Bo,Chu, Shijin,Peng, Rufang,Shang, Yu,Tan, Bisheng. "Novel insensitive energetic-cocrystal-based BTO with good comprehensive properties". . p. 1784 - 1790. Retrieved 2018.
• 2、 Ando, Akihiro,Hasebe, Hayu,Hayashi, Masahiko,Kim, Hojin,Matsubara, Ryosuke,Tsuneda, Takao. "Synthesis and Synthetic Application of Chloro- And Bromofuroxans". . p. 5959 - 5972. Retrieved 2020.
• 3、 Wingard, Leah A.,Guzmán, Pablo E.,Sabatini, Jesse J.. "A Chlorine Gas-Free Synthesis of Dichloroglyoxime". . p. 1686 - 1688. Retrieved 2016.
• 4、 Irngartinger, Hermann,Weber, Anton. "Twofold cycloaddition of [60]fullerene to a bifunctional nitrile oxide". . p. 4137 - 4140. Retrieved 1996.
• 5、 Zhao, Huaibo,McMillan, Alastair J.,Constantin, Timothée,Mykura, Rory C.,Juliá, Fabio,Leonori, Daniele. "Merging Halogen-Atom Transfer (XAT) and Cobalt Catalysis to Override E2-Selectivity in the Elimination of Alkyl Halides: A Mild Route towardcontra-Thermodynamic Olefins". supporting information. p. 14806 - 14813. Retrieved 2021/09/18.
• 6、 Bayrak, Nilüfer,Matarac?-Kara, Emel,Ozbek-Celik, Berna,Tuyun, Ama? Fatih,Y?ld?r?m, Hatice,Y?ld?z, Mahmut. "Bis(Substituted Phenylamino)Glyoxime derivatives: Synthesis, characterization, and antimicrobial evaluation". . . Retrieved 2021/06/16.