4-tert-butyl-2-cyclohexenone oxime

Base Information

• Chemical Name: 4-tert-butyl-2-cyclohexenone oxime
• CAS No.: 215456-38-5
• Molecular Formula: C₁₀H₁₇NO
• Molecular Weight: 167.251
• Mol file: 215456-38-5.mol

Synonyms:4-tert-butyl-2-cyclohexenone oxime

Chemical Property of 4-tert-butyl-2-cyclohexenone oxime

Chemical Property:

Purity/Quality:

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Technology Process of 4-tert-butyl-2-cyclohexenone oxime

There total 1 articles about 4-tert-butyl-2-cyclohexenone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

4-tert-butylcyclohex-2-enone (937-07-5) → 4-tert-butyl-2-cyclohexenone oxime (215456-38-5)

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In methanol; water; at 60 ℃;

DOI:10.1021/jo9812429

Reference yield:

chloro-diphenylphosphine (1079-66-9,74391-44-9) + 4-tert-butyl-2-cyclohexenone oxime (215456-38-5) → C22H26NOP

Guidance literature:

With triethylamine; In dichloromethane; Petroleum ether; at -40 ℃; for 1.75h;

DOI:10.1021/jo9812429

Reference yield:

4-tert-butyl-2-cyclohexenone oxime (215456-38-5) → trans-N-(diphenylphosphinyl)-4-tert-butyl-2-cyclohexenylamine

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / CH₂Cl₂; petroleum ether / 1.75 h / -40 °C

2: DIBAH / tetrahydrofuran / Ambient temperature; further reagent

With diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; dichloromethane; Petroleum ether;

DOI:10.1021/jo9812429

upstream raw materials:

4-tert-butylcyclohex-2-enone

Refernces