(2Z,4Z)-2,4-Hexadiene

Base Information

• Chemical Name: (2Z,4Z)-2,4-Hexadiene
• CAS No.: 6108-61-8
• Molecular Formula: C6H10
• Molecular Weight: 82.1454
• Hs Code.: 2901299090
• UNII: GBO62BQE9B
• DSSTox Substance ID: DTXSID00873539
• Wikidata: Q27279016
• Mol file: 6108-61-8.mol

Synonyms:cis,cis-2,4-Hexadiene;(2Z,4Z)-2,4-Hexadiene;6108-61-8;2,4-Hexadiene, (Z,Z)-;(z,z)-2,4-hexadiene;(Z),(Z)-2,4-Hexadiene;(2Z,4Z)-hexa-2,4-diene;2,4-Hexadiene, (2Z,4Z)-;UNII-GBO62BQE9B;GBO62BQE9B;(Z),(Z)-CH3CH=CHCH=CHCH3;cis-2,cis-4-Hexadiene;cis-2-cis-4-hexadienen;DTXSID00873539;APPOKADJQUIAHP-GLIMQPGKSA-N;J469.959I;Q27279016

Chemical Property of (2Z,4Z)-2,4-Hexadiene

Chemical Property:

• Melting Point: -94.9°C (estimate)
• Refractive Index: 1.4470
• Boiling Point: 84.93°C
• PSA: 0.00000
• Density: 0.7150
• LogP: 2.13860
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 82.078250319
• Heavy Atom Count: 6
• Complexity: 48.4

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CC=CC
• Isomeric SMILES: C/C=C\C=C/C

Technology Process of (2Z,4Z)-2,4-Hexadiene

There total 29 articles about (2Z,4Z)-2,4-Hexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

(2E,4E)-hexa-2,4-diene (5194-51-4) → (E,Z)-2,4-hexadiene (5194-50-3) + 1,3-hexadiene (20237-34-7) + cis,cis-2,4-Hexadien (6108-61-8)

Guidance literature:

In gas; under 0.1 - 0.2 Torr; Irradiation; radio frequency plasma;

DOI:10.1021/ja00277a036

Reference yield: 4.0%

1,3-hexadiene (20237-34-7) → (2E,4E)-hexa-2,4-diene (5194-51-4) + (E,Z)-2,4-hexadiene (5194-50-3) + cis,cis-2,4-Hexadien (6108-61-8)

Guidance literature:

In gas; under 0.1 - 0.2 Torr; Irradiation; radio frequency plasma;

DOI:10.1021/ja00277a036

Reference yield:

cis-1,4-hexadiene (7318-67-4) → (2E,4E)-hexa-2,4-diene (5194-51-4) + (E,Z)-2,4-hexadiene (5194-50-3) + hexa-1,3-diene (592-48-3) + cis,cis-2,4-Hexadien (6108-61-8)

Guidance literature:

With isopropylmagnesium bromide; bis(cyclopentadienyl)titanium dichloride; In diethyl ether; at 20 ℃; for 1h; Product distribution; Mechanism;

upstream raw materials:

thiophene

methylmagnesium bromide

selenophene

Tellurophen

Downstream raw materials:

5,8-dihydro-cis-5,8-dimethyl-2-phenyl-1H-<1,2,4>triazolo<1,2a>pyridazine-1,3(2H)-dione

2-trimethylsilyl-1,3,5-trimethylbenzene

cis-2-methyl-3-(cis-1-propenyl)-1,1-dimesitylsilirane

1-Chloro-4-((Z)-(1R,2R)-2-chloro-1-methyl-pent-3-enylsulfanyl)-benzene

Refernces

• 1、 Bzier, David,Brookhart, Maurice. "Applications of PC(sp3)P iridium complexes in transfer dehydrogenation of alkanes". . p. 3411 - 3420. Retrieved 2015/02/19.
• 2、 Lyons, Thomas W.,Guironnet, Damien,Findlater, Michael,Brookhart, Maurice. "Synthesis of p-xylene from ethylene". supporting information. p. 15708 - 15711,4. Retrieved 2012/12/11.