bis(difluorothio)nitronium hexafluoroarsenate(V)

Base Information

• Chemical Name: bis(difluorothio)nitronium hexafluoroarsenate(V)
• CAS No.: 88446-29-1
• Molecular Formula: AsF₆*F₄NS₂
• Molecular Weight: 343.044
• Mol file: 88446-29-1.mol

Synonyms:bis(difluorothio)nitronium hexafluoroarsenate(V)

Chemical Property of bis(difluorothio)nitronium hexafluoroarsenate(V)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis(difluorothio)nitronium hexafluoroarsenate(V)

There total 3 articles about bis(difluorothio)nitronium hexafluoroarsenate(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

xenon fluoride + dithionitronium hexafluoroarsenate (80485-40-1) → bis(difluorothio)nitronium hexafluoroarsenate(V) (88446-29-1) + sulfur(VI) hexafluoride (2551-62-4)

Guidance literature:

With fluorosulfonyl fluoride; In not given; XeF2 was condensed onto a frozen mixure of S2NAsF6 and SO2F2, mixt. wasstirred and shaken for 0.5 h at 0°C, mixt. was stirred at room temp. for 12h; volatiles were removed, product was dissolved in SO2, than SO2 was removed , product was recrystd. from SO2-SO2ClF; elem. anal.;

DOI:10.1039/DT9830001961

Reference yield:

xenon fluoride + dithionitronium hexafluoroarsenate (80485-40-1) → bis(difluorothio)nitronium hexafluoroarsenate(V) (88446-29-1) + difluoro-dithionitronium hexafluoroarsenate(V) + sulfur tetrafluoride (7783-60-0)

Guidance literature:

With fluorosulfonyl fluoride; In not given; SO2F2 and XeF2 were condensed onto S2NAsF6, mixt. was held at 0°C, with agitation, for 1h, 2 h at room temp.; volatiles were removed, products were not isolated; products were analized by IR;

DOI:10.1039/DT9830001961

Reference yield:

dithionitronium hexafluoroarsenate (80485-40-1) + fluorine (7782-41-4) → {SF3}(1+)*{AsF6}(1-)=SF3AsF6 (30313-36-1) + bis(difluorothio)nitronium hexafluoroarsenate(V) (88446-29-1) + difluoro-dithionitronium hexafluoroarsenate(V) + sulfur(VI) hexafluoride (2551-62-4)

Guidance literature:

With fluorosulfonyl fluoride; In not given; SO2F2 and F2 were added to S2NAsF6 at -196°C, mixt. was stirred for 4 h while held at -78°C, mixt. was stirred at room temp. for 20h; volatiles were removed, products were not isolated; products were analized by IR;

DOI:10.1039/DT9830001961

upstream raw materials:

dithionitronium hexafluoroarsenate

fluorine

Downstream raw materials:

thiazyl fluoride

cesium hexafluoroarsenate

sulfur tetrafluoride

thionyl fluoride

Refernces