4,10-bis((4-hexylphenyl)ethynyl)anthanthrone

Base Information

• Chemical Name: 4,10-bis((4-hexylphenyl)ethynyl)anthanthrone
• CAS No.: 1574519-01-9
• Molecular Formula: C₅₀H₄₂O₂
• Molecular Weight: 674.882
• Mol file: 1574519-01-9.mol

Synonyms:4,10-bis((4-hexylphenyl)ethynyl)anthanthrone

Chemical Property of 4,10-bis((4-hexylphenyl)ethynyl)anthanthrone

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 4,10-bis((4-hexylphenyl)ethynyl)anthanthrone

There total 1 articles about 4,10-bis((4-hexylphenyl)ethynyl)anthanthrone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4,10-dibromoanthanthrone (4378-61-4) + 4-hexylphenylacetylene (79887-11-9) → 4,10-bis((4-hexylphenyl)ethynyl)anthanthrone (1574519-01-9)

Guidance literature:

With tris(1-adamantyl)phosphine; palladium diacetate; triethylamine; In water; at 80 ℃; for 1h; Milling;

DOI:10.1039/d1sc05257h

Reference yield: 25.0%

4,10-bis((4-hexylphenyl)ethynyl)anthanthrone (1574519-01-9) + 4-hexylphenylacetylene (79887-11-9) → 4,6,10,12-tetrakis((4-hexylphenyl)ethynyl)anthanthrene

Guidance literature:

4-hexylphenylacetylene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.333333h; Inert atmosphere;

4,10-bis((4-hexylphenyl)ethynyl)anthanthrone; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere;

With hydrogenchloride; tin(II) chloride dihdyrate; In tetrahydrofuran; hexane; water; for 0.333333h;

DOI:10.1021/jo402674m

Reference yield: 25.0%

4,10-bis((4-hexylphenyl)ethynyl)anthanthrone (1574519-01-9) + C14H17Li (1574519-40-6) → 4,6,10,12-tetrakis((4-hexylphenyl)ethynyl)anthanthrene

Guidance literature:

With hydrogenchloride; tin(ll) chloride; In tetrahydrofuran; water;

DOI:10.1021/jo402674m

upstream raw materials:

4,10-dibromoanthanthrone

4-hexylphenylacetylene

Refernces

• 1、 Feng, Chi,Gao, Yunpeng,Ito, Hajime,Kubota, Koji,Seo, Tamae. "Efficient access to materials-oriented aromatic alkynes: Via the mechanochemical Sonogashira coupling of solid aryl halides with large polycyclic conjugated systems". . p. 430 - 438. Retrieved 2022/01/22.