Dipropyl ketoxime

Base Information

• Chemical Name: Dipropyl ketoxime
• CAS No.: 1188-63-2
• Molecular Formula: C7H15 N O
• Molecular Weight: 129.202
• Hs Code.: 2928000090
• NSC Number: 32351
• DSSTox Substance ID: DTXSID30922786
• Nikkaji Number: J108.744D
• Mol file: 1188-63-2.mol

Synonyms:Dipropyl ketoxime;4-Heptanone oxime;Dipropyl ketone oxime;4-Heptanone, oxime;N-heptan-4-ylidenehydroxylamine;1188-63-2;heptan-4-one oxime;SCHEMBL758250;DTXSID30922786;VLVVDHDKRHWUSQ-UHFFFAOYSA-N;NSC32351;NSC-32351;AKOS008939679

Chemical Property of Dipropyl ketoxime

Chemical Property:

• Vapor Pressure: 0.0887mmHg at 25°C
• Boiling Point: 207.8°Cat760mmHg
• Flash Point: 109.6°C
• PSA: 32.59000
• Density: 0.88g/cm³
• LogP: 2.41680
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 129.115364102
• Heavy Atom Count: 9
• Complexity: 80.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC(=NO)CCC

Technology Process of Dipropyl ketoxime

There total 14 articles about Dipropyl ketoxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-heptanone (123-19-3) → 4-heptanone oxime (1188-63-2)

Guidance literature:

With hydroxylamine;

Reference yield:

n-heptane (142-82-5) → 4-heptanone oxime (1188-63-2)

Guidance literature:

With nitrosylchloride; Irradiation_.im Sonnenlicht;

DOI:10.1002/1521-4095(200006)12:13<989::AID-ADMA989>3.0.CO;2-K

Reference yield:

4-heptanone (123-19-3) → 4-heptanone oxime (1188-63-2) + 4-heptylideneimine (87113-11-9)

Guidance literature:

With ammonium hydroxide; dihydrogen peroxide; Ti-V-silicalite; at 54.9 ℃; for 5h; under 760 Torr; Product distribution; Mechanism; var. of catalyst, time;

DOI:10.1039/c39950002281

upstream raw materials:

4-heptanone

4-chloro-4-nitrosoheptane

bis(4-nitrosoheptane)

n-heptane

Downstream raw materials:

C₁₅H₁₉Cl₂NO₃

4-heptanone

di-n-propyl ketone oxime O-allyl ether

N-propylbutyrylamide

Refernces

• 1、 Lynn,Hilton. "-". . p. 646. Retrieved 1922.
• 2、 Scaffidi-Domianello, Yulia Yu.,Meelich, Kristof,Jakupec, Michael A.,Arion, Vladimir B.,Kukushkin, Vadim Yu.,Galanski, Markus,Keppler, Bernhard K.. "Novel cis- and trans-configured bis(oxime)platinum(II) complexes: Synthesis, characterization, and cytotoxic activity". experimental part. p. 5669 - 5678. Retrieved 2010/08/06.