((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium

Base Information

• Chemical Name: ((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium
• CAS No.: 1007582-87-7
• Molecular Formula: C₂₁H₂₈ClN₂O₃P₂Re
• Molecular Weight: 640.072
• Mol file: 1007582-87-7.mol

Synonyms:((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium

Chemical Property of ((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium

Chemical Property:

Purity/Quality:

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Technology Process of ((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium

There total 1 articles about ((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

rhenium(I) pentacarbonyl chloride (14099-01-5) + (R,R)-(-)-2,3-bis(tert-butylmethylphosphino)qinoxaline (1107608-80-9,866081-62-1,959705-18-1) → ((R,R)-(-)-2,3-bis(tert-butylmethylphosphino)quinoxaline)tricarbonylchlororhenium (1007582-87-7)

Guidance literature:

In dichloromethane; toluene; under Ar atm. mixt. ligand and Re complex in toluene-CH2Cl2 (3:1) was heated to reflux for 4 h; soln. was concd. in vacuo, Et2O was added at 0°C, ppt. was filtered, washed with Et2O and dried; elem. anal.;

DOI:10.1021/om700755y

upstream raw materials:

rhenium(I) pentacarbonyl chloride

(R,R)-(-)-2,3-bis(tert-butylmethylphosphino)qinoxaline

Refernces