diphenyleneiodonium trifluoromethanesulfonate

Base Information

• Chemical Name: diphenyleneiodonium trifluoromethanesulfonate
• CAS No.: 189999-35-7
• Molecular Formula: CF₃O₃S*C₁₂H₈I
• Molecular Weight: 428.17
• Mol file: 189999-35-7.mol

Synonyms:[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate

Chemical Property of diphenyleneiodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenyleneiodonium trifluoromethanesulfonate

There total 10 articles about diphenyleneiodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C21H20IN2(1+)*CF3O3S(1-) → [1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate (189999-35-7) + 4-pyrrolidin-1-ylpyridine (2456-81-7)

Guidance literature:

In acetonitrile; at 20 ℃; Equilibrium constant; Inert atmosphere;

DOI:10.1021/jacs.9b12998

Reference yield:

C19H21IN(1+)*CF3O3S(1-) → Quinuclidine (100-76-5) + [1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate (189999-35-7)

Guidance literature:

In acetonitrile; at 20 ℃; Equilibrium constant; Inert atmosphere;

DOI:10.1021/jacs.9b12998

Reference yield:

tetrabutylammonium trifluoromethylsulfonate (35895-70-6) + diphenyleneiodonium chloride → [1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate (189999-35-7) + tetrabutyl-ammonium chloride (1112-67-0)

Guidance literature:

In acetonitrile; at 20 ℃; Equilibrium constant; Inert atmosphere;

DOI:10.1021/jacs.9b12998

upstream raw materials:

tetrabutylammonium trifluoromethylsulfonate

Downstream raw materials:

9-(4-methylphenyl)-9H-carbazole

9H-carbazole

9-((4-ethylphenyl)sulfonyl)-9H-carbazole

9-tosyl-9H-carbazole

Refernces