platinum tetrakis(pentafluorophenyl)porpholactone

Base Information

• Chemical Name: platinum tetrakis(pentafluorophenyl)porpholactone
• CAS No.: 478308-82-6
• Molecular Formula: C₄₃H₆F₂₀N₄O₂Pt
• Molecular Weight: 1185.59
• Mol file: 478308-82-6.mol

Synonyms:platinum tetrakis(pentafluorophenyl)porpholactone

Chemical Property of platinum tetrakis(pentafluorophenyl)porpholactone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of platinum tetrakis(pentafluorophenyl)porpholactone

There total 4 articles about platinum tetrakis(pentafluorophenyl)porpholactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

C54H18F20N6O4OsPt → platinum tetrakis(pentafluorophenyl)porpholactone (478308-82-6)

Guidance literature:

With cethyltrimethylammonium permanganate; In dichloromethane; at 20 ℃; for 0.5h; Darkness;

DOI:10.1021/acs.joc.8b02628

Reference yield: 30.0%

[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrinato]platinum(II) (109781-47-7) + potassium peroxymonosulfate → platinum tetrakis(pentafluorophenyl)porpholactone (478308-82-6) + zinc(II) 5,10,15,20-tetrakis(pentafluorophenyl)porpholactone (119998-79-7)

Guidance literature:

With [2,2]bipyridinyl; ruthenium trichloride; sodium hydroxide; In water; 1,2-dichloro-ethane; at 80 ℃; for 4h;

DOI:10.1002/adsc.201200720

Reference yield:

tetrakis(pentafluorophenyl)porphyrin (25440-14-6) → platinum tetrakis(pentafluorophenyl)porpholactone (478308-82-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: osmium(VIII) oxide; pyridine / chloroform / 24 h / 20 °C

1.2: 48 h / 20 °C

2.1: cethyltrimethylammonium permanganate / dichloromethane / 3 h / 20 °C

3.1: benzonitrile / Reflux

With pyridine; osmium(VIII) oxide; cethyltrimethylammonium permanganate; In dichloromethane; chloroform; benzonitrile;

DOI:10.1039/c4ob00697f

upstream raw materials:

[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrinato]platinum(II)

tetrakis(pentafluorophenyl)porphyrin

Downstream raw materials:

[meso-5,10,15,20-tetrakis(4-[2-(2-methoxyethoxy)ethane]thioxytetra-2,3,5,6-fluorophenyl)porpholactonato]platinum(II)

Refernces

• 1、 Worlinsky, Jill L.,Halepas, Steven,Brueckner, Christian. "PEGylated meso-arylporpholactone metal complexes as optical cyanide sensors in water". . p. 3991 - 4001. Retrieved 2014/06/09.