di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite

Base Information

• Chemical Name: di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite
• CAS No.: 87651-42-1
• Molecular Formula: C₁₂H₁₁F₈O₂P
• Molecular Weight: 370.179
• Mol file: 87651-42-1.mol

Synonyms:di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite

Chemical Property of di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite

There total 1 articles about di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2,2,3,3-tetrafluoropropanol (76-37-9) + Dichlorophenylphosphine (644-97-3) → di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite (87651-42-1)

Guidance literature:

at 20 - 25 ℃;

DOI:10.1134/S1070363210030096

Reference yield: 95.0%

chloral hydrate (302-17-0) + di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite (87651-42-1) → 2,2,3,3-tetrafluoropropanol (76-37-9) + (1,1,3-trihydrotetrafluoropropyl) (1-hydroxy-2,2,2-trichloroethyl)phenylphosphinate (1235818-80-0)

Guidance literature:

In benzene; at 30 - 40 ℃; for 12h; Inert atmosphere;

DOI:10.1134/S1070363210030096

Reference yield:

tetrachloromethane (56-23-5) + di(1,1,3-trihydrotetrafluoropropyl)phenyl phosphonite (87651-42-1) → Phenyl-trichloromethyl-phosphinic acid 2,2,3,3-tetrafluoro-propyl ester

Guidance literature:

In acetonitrile; at 150 - 160 ℃; for 30h;

upstream raw materials:

2,2,3,3-tetrafluoropropanol

Dichlorophenylphosphine

Downstream raw materials:

2,2,3,3-tetrafluoropropanol

(1,1,3-trihydrotetrafluoropropyl) (1-hydroxy-2,2,2-trichloroethyl)phenylphosphinate

Refernces

• 1、 Krutikov, V. I.,Lavrent'ev, A. N.. "REACTIONS OF P(III) ESTERS WITH CARBON TETRACHLORIDE. VII. INFLUENCE OF THE SOLVENT ON THE REACTION RATE". . p. 2238 - 2242. Retrieved 2007/10/02.