(C₆H₅)3SnCu

Base Information

• Chemical Name: (C₆H₅)3SnCu
• CAS No.: 83569-22-6
• Molecular Formula: C₁₈H₁₅CuSn
• Molecular Weight: 413.573
• Mol file: 83569-22-6.mol

Synonyms:(C₆H₅)3SnCu

Chemical Property of (C₆H₅)3SnCu

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (C₆H₅)3SnCu

There total 1 articles about (C₆H₅)3SnCu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylstannyllithium (4167-90-2) + copper(I) bromide (7787-70-4) → (C6H5)3SnCu (83569-22-6)

Guidance literature:

With lithium bromide; In tetrahydrofuran; under N2, to stirred suspn. of CuBr in THF added soln. of LiBr in THF, cooled to -60°C, soln. of Ph3SnLi in THF added dropwise, stirred for 30 min at -60°C; not isolated;

DOI:10.1016/S0022-328X(00)98533-4

Reference yield: 95.0%

(C6H5)3SnCu (83569-22-6) + HC2C(CH2)4OSOCH3 (85366-19-4) → 1-(triphenylstannyl)-3,3-tetramethylenepropadiene (85366-25-2)

Guidance literature:

In tetrahydrofuran; under N2, to stannylcopper(I) reagent added at -60°C propargyliccompd., stirred for 1 h at -60°C, poured into satd. soln. of NH4Cl in water contg. NaCN; extd. with ether/pentane, washed with water, dried with MgSO4, evapd. in vac., chromd. (Al2O3-5% H2O/n-hexane);

DOI:10.1016/S0022-328X(00)98533-4

Reference yield: 95.0%

(C6H5)3SnCu (83569-22-6) + Methanesulfonic acid 1,1-dimethyl-prop-2-ynyl ester (76651-91-7) → 1-(triphenylstannyl)-3-methyl-1,2-butadiene (85366-23-0)

Guidance literature:

In tetrahydrofuran; under N2, to stannylcopper(I) reagent added at -60°C propargyliccompd., stirred for 1 h at -60°C, poured into satd. soln. of NH4Cl in water contg. NaCN; extd. with ether/pentane, washed with water, dried with MgSO4, evapd. in vac., chromd. (Al2O3-5% H2O/n-hexane) or crystd. from methanol;

DOI:10.1016/S0022-328X(00)98533-4

upstream raw materials:

triphenylstannyllithium

copper(I) bromide

Downstream raw materials:

allenyltriphenylstannane

2-(triphenylstannyl)-4-methyl-2,3-pentadiene

1-(triphenylstannyl)-3,3-tetramethylenepropadiene

1-(triphenylstannyl)-3-methyl-1,2-butadiene

Refernces