Bismuth oxychloride

Base Information

• Chemical Name: Bismuth oxychloride
• CAS No.: 7787-59-9
• Molecular Formula: BiClO
• Molecular Weight: 260.433
• Hs Code.: 28274990
• UNII: 4ZR792I587
• Wikidata: Q418042
• Mol file: 7787-59-9.mol

Synonyms:Bismuthyl chloride;Bismuth oxochloride;Bismuth oxide chloride;Bismuth(III) oxide chloride;Bismoclite;Basic bismuth chloride;Bismuth chloride oxide;Bismuth subchloride;Bismuthine, chlorooxo-;Chlorooxobismuthine;Pearl white;Pigment white 14;

Chemical Property of Bismuth oxychloride

Chemical Property:

• Appearance/Colour: White lustorus powder
• Melting Point: melts at low red heat [MER06]
• Refractive Index: 2.15
• PSA: 17.07000
• Density: 7.72 g/mL at 25 °C(lit.)
• LogP: 0.57070
• Solubility.: H2O: insoluble(lit.)
• Water Solubility.: Soluble in HCl, HNO3. Insoluble in water, alcohol.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 259.94417
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Bismuth oxychloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [O-2].[Cl-].[Bi+3]
• Physical properties: White powder or tetragonal crystals; density 7.72 g/cm3; practically insoluble in water, alcohol and acetone; soluble in hydrochloric and nitric acids (with decomposition); Ksp 7.0 x 10-9.
• Uses: In face powders; as pigment; manufacture of artificial pearls, dry-cell cathodes. bismuth oxychloride is an inorganic color additive. It is used mostly in makeup manufacturing and rarely in skin care formulations. It may also be used for pearlization in cosmetics. It is used as skin protective's, thickeners, and absorbent agents. It act as a coloring agents in cosmetics.

Technology Process of Bismuth oxychloride

There total 68 articles about Bismuth oxychloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylbismuth dichloride (28719-54-2,507233-69-4,594-30-9) + mercury dichloride → bismuth(III) oxychloride (7787-59-9) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

In ethanol; byproducts: Cl2, HCl; 78°C, 0.5 h;

Reference yield:

triphenylbismuthane (603-33-8) + mercury dichloride → bismuth(III) oxide chloride (7787-59-9) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

In water; byproducts: C6H6;

Reference yield:

bismuth (III) nitrate pentahydrate + potassium chloride → bismuth(III) oxide chloride (7787-59-9)

Guidance literature:

In water; at 150 ℃; for 5h; Autoclave;

DOI:10.1002/chem.201302884

upstream raw materials:

nitric acid

triphenylbismuth dichloride

triphenylbismuthane

water

Downstream raw materials:

bismuth(III) oxide

bismuth(III) chloride

bismuth(III) iodide

chlorine

Refernces

• 1、 Damm, Christine,Doert, Thomas,Ruck, Michael,Smuda, Matthias. "Mechanism of Bi?Ni Phase Formation in a Microwave-Assisted Polyol Process". . . Retrieved 2020.
• 2、 Lei, Liwen,Jin, Huihui,Zhang, Qi,Xu, Jun,Gao, Da,Fu, Zhengyi. "A novel enhanced visible-light-driven photocatalyst via hybridization of nanosized BiOCl and graphitic C3N4". . p. 795 - 803. Retrieved 2015.
• 3、 Liu, Wei,Yang, Qi,Wang, Zhen,Lv, Xiaofan,Yang, Zhilin. "Photocatalytic degradation of trichloroethylene over BiOCl under UV irradiation". . . Retrieved 2018.
• 4、 Miao, Yingchun,Lian, Zichao,Huo, Yuning,Li, Hexing. "Microwave-assisted ionothermal synthesis of hierarchical microcube-like BiOBr with enhanced photocatalytic activity". . p. 1411 - 1417. Retrieved 2018.
• 5、 Gopalakrishnan,Sivakumar,Ramesha,Thangadurai,Subbanna. "Transformations of ruddlesden-popper oxides to new layered perovskite oxides by metathesis reactions". . p. 6237 - 6241. Retrieved 2000.
• 6、 Guang, Lu,Hui, Wang,Xuejun, Zou. "Effect of drying temperatures on structural performance and photocatalytic activity of BiOCl synthesized by a soft chemical method". . p. 259 - 264. Retrieved 2016.
• 7、 Sarkar, Ratna,Das, Dimitra,Kumar Das, Bikram,Mitra, Anuradha,Das, Nirmalya S.,Sarkar, Subrata,Chattopadhyay, Kalyan K.. "Hollow micro-spherical bismuth oxy-chloride for superior visible light induced dye-sensitized photocatalytic activity and its theoretical insight". . . Retrieved 2020.
• 8、 Yao, Hanyu,Li, Haiping,Hu, Tingxia,Hou, Wanguo. "Solvent-Free Synthesis of Bismuth Oxychloride Microflower/Nanosheet Homojunctions for Photoactivity Enhancement". . p. 3726 - 3735. Retrieved 2018.