2-(CHLOROMERCURI)PHENOL

Base Information

• Chemical Name: 2-(CHLOROMERCURI)PHENOL
• CAS No.: 90-03-9
• Molecular Formula: C6H5 Cl Hg O
• Molecular Weight: 329.148
• European Community (EC) Number: 201-962-6,215-308-2
• NSC Number: 5579
• DSSTox Substance ID: DTXSID2042224
• Wikidata: Q27286754
• NCI Thesaurus Code: C174854
• Mol file: 90-03-9.mol

Synonyms:Mercury,chloro(o-hydroxyphenyl)- (8CI); Phenol, o-(chloromercuri)- (6CI,7CI);(2-Hydroxyphenyl)mercuric chloride; (2-Hydroxyphenyl)mercury chloride;(o-Hydroxyphenyl)mercuric chloride; (o-Hydroxyphenyl)mercury chloride;2-(Chloromercurio)phenol; Mercufenol chloride; Myringacaine Drops; NP-27; NSC5579; Salicresin Fluid; U 7743; o-(Chloromercuri)phenol;o-(Chloromercurio)phenol; o-Mercurihydroxyphenyl chloride

Chemical Property of 2-(CHLOROMERCURI)PHENOL

Chemical Property:

• Melting Point: 150-152°
• Boiling Point: 58.5°C
• PSA: 20.23000
• LogP: 1.25380
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 329.973536
• Heavy Atom Count: 9
• Complexity: 89.1

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): Skin irritant. TLV: 0.01 (Hg) mg/m³.
• Hazard Codes: Skin irritant. TLV: 0.01 (Hg) mg/m3.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: C1=CC=C(C(=C1)O)[Hg]Cl

Technology Process of 2-(CHLOROMERCURI)PHENOL

There total 2 articles about 2-(CHLOROMERCURI)PHENOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

mercury(II) diacetate (1600-27-7) + sodium chloride (7647-14-5) + phenol (108-95-2,27073-41-2) → 4-hydroxyphenyl mercury(II) chloride (623-07-4) + (2-hydroxyphenyl)mercury chloride (90-03-9)

Guidance literature:

mercury(II) diacetate; phenol; In water; for 0.166667h; Heating;

sodium chloride; In water; Heating;

Reference yield:

sodium hydroxide (1310-73-2) + phenol (108-95-2,27073-41-2) → 4-hydroxyphenyl mercury(II) chloride (623-07-4) + (2-hydroxyphenyl)mercury chloride (90-03-9)

Guidance literature:

With mercury dichloride; In water; byproducts: oxyphenyldimercury chloride; at boiling;;

Reference yield: 91.0%

1,4-diphenyl-3-butene-2-one (5409-59-6) + (2-hydroxyphenyl)mercury chloride (90-03-9) → 4-phenyl-2-methylchroman-2-ol (81603-20-5)

Guidance literature:

With hydrogenchloride; tetrabutyl-ammonium chloride; palladium dichloride; In dichloromethane; for 2h; Ambient temperature;

DOI:10.1021/jo00136a036

upstream raw materials:

sodium hydroxide

phenol

mercury(II) diacetate

sodium chloride

Downstream raw materials:

methyl 2-coumarate

4-phenyl-2-methylchroman-2-ol

4-Phenyl-2-((E)-styryl)-4H-chromene

2,2'-dihydroxybenzophenone

Refernces