CYCLOHEXYL VINYL ETHER

Base Information

• Chemical Name: CYCLOHEXYL VINYL ETHER
• CAS No.: 2182-55-0
• Deprecated CAS: 877854-39-2,2056117-92-9
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• Hs Code.: 29092000
• European Community (EC) Number: 218-561-7
• NSC Number: 75856
• UNII: G76WFY9VJP
• DSSTox Substance ID: DTXSID1074339
• Nikkaji Number: J23.458C
• Wikidata: Q72460170
• Mol file: 2182-55-0.mol

Synonyms:Ether,cyclohexyl vinyl (6CI,7CI,8CI);(Cyclohexyloxy)ethene;CHVE;NSC 75856;

Chemical Property of CYCLOHEXYL VINYL ETHER

Chemical Property:

• Vapor Pressure: 1.3mmHg at 25°C
• Refractive Index: n20/D 1.454(lit.)
• Boiling Point: 179.1 °C at 760 mmHg
• Flash Point: 53.5 °C
• PSA: 9.23000
• Density: 0.87 g/cm³
• LogP: 2.47920
• Water Solubility.: 330mg/L at 20℃
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 126.104465066
• Heavy Atom Count: 9
• Complexity: 82.6

Purity/Quality:

99.9% ^*data from raw suppliers

Cyclohexyl vinyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-38-19
• Safety Statements: 16-23-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=COC1CCCCC1

Technology Process of CYCLOHEXYL VINYL ETHER

There total 7 articles about CYCLOHEXYL VINYL ETHER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

calcium carbide (75-20-7) + cyclohexanol (108-93-0) → vinyl cyclohexyl ether (2182-55-0)

Guidance literature:

calcium carbide; cyclohexanol; With potassium fluoride; potassium hydroxide; In dimethyl sulfoxide; at 20 ℃; for 0.0833333h;

With water; In dimethyl sulfoxide; at 130 ℃; for 3h; Sealed tube;

DOI:10.1039/c7gc00724h

Reference yield: 88.0%

acetylene (74-86-2,25067-58-7) + cyclohexanol (108-93-0) → vinyl cyclohexyl ether (2182-55-0)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 100 ℃; for 4h; atmospheric pressure;

DOI:10.1007/s11178-005-0222-y

Reference yield:

ethyl vinyl ether (109-92-2,25104-37-4) + cyclohexanol (108-93-0) → vinyl cyclohexyl ether (2182-55-0)

Guidance literature:

With mercury(II) diacetate; for 240h; Ambient temperature;

DOI:10.1080/00397919208019270

upstream raw materials:

acetylene

cyclohexanol

2-ethylhexyl vinyl ether

ethyl vinyl ether

Downstream raw materials:

acetaldehyde dicyclohexyl acetal

1-Cyclohexyloxy-1--aethan

Refernces

• 1、 Werner, Georg,Rodygin, Konstantin S.,Kostin, Anton A.,Gordeev, Evgeniy G.,Kashin, Alexey S.,Ananikov, Valentine P.. "A solid acetylene reagent with enhanced reactivity: Fluoride-mediated functionalization of alcohols and phenols". supporting information. p. 3032 - 3041. Retrieved 2017/07/24.
• 2、 Nakamura, Aki,Tokunaga, Makoto. "Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids". . p. 3729 - 3732. Retrieved 2008/09/20.