6-Nonen-1-ol, (6Z)-

Base Information

• Chemical Name: 6-Nonen-1-ol, (6Z)-
• CAS No.: 35854-86-5
• Molecular Formula: C₉H₁₈O
• Molecular Weight: 142.241
• Hs Code.: 29052900
• European Community (EC) Number: 252-764-1
• UNII: 05401NS64Z
• DSSTox Substance ID: DTXSID0047587
• Nikkaji Number: J208.792H
• Wikidata: Q27236069
• Metabolomics Workbench ID: 3225
• ChEMBL ID: CHEMBL3182724
• Mol file: 35854-86-5.mol

Synonyms:(Z)-6-Nonen-1-ol;

Chemical Property of 6-Nonen-1-ol, (6Z)-

Chemical Property:

• Appearance/Colour: Colorless to pale yellow liquid
• Vapor Pressure: 0.0777mmHg at 25°C
• Refractive Index: n20/D 1.449(lit.)
• Boiling Point: 201.027 °C at 760 mmHg
• PKA: 15.18±0.10(Predicted)
• Flash Point: 74.248 °C
• PSA: 20.23000
• Density: 0.85 g/cm³
• LogP: 2.50530
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 142.135765193
• Heavy Atom Count: 10
• Complexity: 76.8

Purity/Quality:

cis-6-Nonen-1-ol >90.0%(GC) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: S23:Do not inhale gas/fumes/vapour/spray.; S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCC=CCCCCCO
• Isomeric SMILES: CC/C=C\CCCCCO
• Uses: Food additive.

Technology Process of 6-Nonen-1-ol, (6Z)-

There total 21 articles about 6-Nonen-1-ol, (6Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1-Tetrahydropyranyloxy-non-6(Z)-ene (87298-22-4) → (Z)-6-nonenol (31502-19-9,40709-05-5,35854-86-5)

Guidance literature:

With pyridine; toluene-4-sulfonic acid; In methanol; at 55 ℃; for 6h;

Reference yield:

(6R,7S)-6-(Diphenyl-phosphinoyl)-nonane-1,7-diol (146964-30-9,146964-31-0) → (E)-6-nonen-1-ol (31502-19-9) + (Z)-6-nonenol (31502-19-9,40709-05-5,35854-86-5)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 50 ℃; for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Reference yield:

hexahydro-2H-oxepin-2-one (502-44-3,24980-41-4,80137-66-2) + propylidenetriphenylphosphorane (16666-78-7) → (E)-6-nonen-1-ol (31502-19-9) + (Z)-6-nonenol (31502-19-9,40709-05-5,35854-86-5)

Guidance literature:

With diisobutylaluminium hydride; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) toluene, hexane, -78 deg C, 30 min., 2.) THF, room temp., 30 min.;

DOI:10.1055/s-1980-29304

upstream raw materials:

trimethylene oxide

(Z)-1-Bromohex-3-ene

hexahydro-2H-oxepin-2-one

propylidenetriphenylphosphorane

Downstream raw materials:

cis-6-nonenal

(Z)-non-6-enylphenylamine

(Z)-oxacycloheptadec-11-en-2-one

(E)-oxacycloheptadec-11-en-2-one

Refernces

• 1、 Ayrey, Peter M.,Bolton, Michael A.,Buss, Antony D.,Greeves, Nicholas,Levin, Daniel,et al.. "Stereochemically controlled Synthesis of Unsaturated Alcohols by the Horner-Wittig Reaction". . p. 3407 - 3418. Retrieved 2007/10/02.
• 2、 Odinokov, V. N.,Ishmuratov, G. Yu.,Galeeva, R. I.,Kharisov, R. Ya.,Sokol'skaya, O. V.,at al.. "OZONOLYSIS OF ALKENES AND REACTIONS OF POLYFUNCTIONAL COMPOUNDS. XXXV. SYNTHESIS OF 8Z-DODECENYL- AND 11Z-TETRADECENYL ACETATES FROM THE CYCLIC DIMER OF BUTADIENE". . p. 646 - 651. Retrieved 2007/10/02.